Diagnosis of the risk of soil pollution and the performance of measures for the recovery of contaminated soil requires proper monitoring of the extent of soil function damage and its recovery process. Soil enzymes reveal ecosystem perturbations, are sensitive to management choices, and have been used as indicators of biogeochemical cycles, organic matter degradation, and soil remediation processes. Thus, enzymes can indicate, along with other physical or chemical properties, soil quality. In this paper, we review the effects of soil pollutants [toxic trace elements (TTE), and petroleum hydrocarbons (PHC)] on enzymatic activities and evaluate the usefulness of soil enzyme’s activity for monitoring recovery processes in contaminated soil. Soil enzymes can be said to be a powerful means of monitoring to properly indicate the degree of deterioration of soil quality caused by soil pollution and to diagnose the process of functional recovery of contaminated soil. Further research is needed to establish the quantitative relationships between the soil physico-chemical properties and enzyme activity and the effect of soil remediation on the functional recovery of soil-related to soil quality.

The present study was conducted to ascertain the potential of spent coffee grounds (SCGs) as an alternative adsorbent for the removal of cadmium (Cd) from aqueous solutions. Therefore, Cd adsorption batch tests, using SCGs that had not undergone any chemical pretreatment, were conducted using Cd solutions with a wide concentration range (i.e., 0.1–120 mM) under various adsorption conditions, e.g., ion strength, pH, and solid/solution ratio. For comparison, zeolite, as a well-known common representative adsorbent, was included to determine the adsorption efficiency. The adsorption capacity of the SCGs increased with the decreasing ionic strength of the test solution from 200 to 0 mM of Ca(NO₃)₂ and the increasing solid:solution ratio from 1:4 to 1:400. The most significant factor influencing the adsorption capacity of the SCGs was the pH of the test solution, with increases in the adsorption capacity as the initial solution pH was increased from 2 to 10. However, the rate for Cd removal remained constant, at 71.19%, when the initial solution pH was between 4 and 8 due to the buffer capacity of SCGs. The obtained data were fitted with the Freundlich, Langmuir, and Dubinin-Radushkevich isotherm models. The Langmuir isotherm provided the best correlation for Cd adsorption onto SCGs (R² = 0.96) and zeolite (R² = 0.92), and the maximum Cd adsorption capacity of the SCGs was 19.32 mg g^-1, which was higher than that of zeolite (13.91 mg g⁻¹). These results mean that the SCGs can be utilized as alternative low-cost biosorbents to replace conventional adsorption materials.

Global governance of soil resources as well as revitalizations and remediation of degraded areas seem to be necessary actions for sustainable development. A great deal of effort has gone into developing remediation technologies to remove or reduce the impact of these contaminants in the environment. However, contaminated soil remediations in stringent conditions deteriorate soil properties and functions and create the need for efficient soil revitalization measures. Soil washing (SW) and thermal desorption (TD) are commonly used to remediate contaminated soil and can significantly reduce the contaminant, sometimes to safe levels where reuse can be considered; however, the effects of treatment on soil quality must be understood in order to support redevelopment after remediation. In this review, we discussed the effects of SW and TD on soil properties, including subsequent soil quality and health. Furthermore, the importance of these techniques for remediation and reclamation strategies was discussed. Some restoration strategies were also proposed for the recovery of soil quality. In addition, remediated and revitalized soil can be reused for various purposes, which can be accepted as an implementation of sustainable remediation. This review concludes with an outlook of future research efforts that will further shift SW and TD toward sustainable remediation.

For sustainable soil management, there is an increasing demand for soil quality, resilience, and health assessment. After remediation of petroleum hydrocarbon (PHC)-contaminated soils, changes in the physicochemical and ecological characteristics of the soil were investigated. Two kinds of remediation technologies were applied to contaminated soils: land farming (LF) and high temperature thermal desorption (HTTD). As a result of total petroleum hydrocarbons (TPH), PHC-contaminated soils were efficiently remediated by LF and HTTD. The soil health could not be completely recovered after the removal of pollutants due to adverse changes in the soil properties, especially in soil enzyme activities. Therefore, monitoring is necessary for accurate estimation of soil ecotoxicity and effective remediation, and additional soil management, such as fertilizer application or organic amendments, is needed to restore soil heath. In the case of HTTD, soil ecological properties are severely changed during the remediation process. The decision to reuse or recycle remediated soils should reflect changes in soil quality. HTTD is a harsh remediation method that results in deterioration of soil fertility and ecological functions. Alternatives, such as low-temperature thermal desorption or additional soil management using fertilizer or organic amendments, for example, are needed.

For the ammonia generated in Korea, the contribution rate of livestock manure is high, and a large amount of ammonia (NH₃) is emitted into the atmosphere during the soil application process. Volatilization of NH₃ is affected by soil characteristics as well as manure characteristics, but the current inventory does not sufficiently reflect this. This study was conducted to confirm the change of the NH₃ emitted from liquid fertilizer (LF) due to soil pH and to evaluate the impacts of biochar (BC) on the suppression of NH₃ volatilization. Estimating the NH₃ emission flux using the chamber for 24 soils after LF treatment, it showed a tendency to increase exponentially as the pH in soil increased from 4 to 7. In addition, the parallel treatment of BC and LF increased the soil pH, thereby increasing the NH₃ emission flux. The rise of soil pH due to LF treatment is a temporary phenomenon that appears in the early stage, but since NH₃ volatilization is also highest at the beginning of LF application, the effect of soil characteristics on emission factor and its inventory should be considered when calculating the amount of NH₃ emissions. Therefore, follow-up studies such as subdividing and enhancing the NH₃ emission factor by soil characteristics and developing a reduction coefficient to certify the amount of emission reduction are needed.