Polymer composites are widely used in various fields of production and life, and the study of preparing environmentally friendly and flame retardant clay/polymer composites has gradually become a global research hotspot. But how to efficiently surface modify clay and apply it to the field of flame retardant polymers is still a potential challenge. One of the most commonly used surface modification methods is the modification of clay with silane coupling agents. The hydrolysable groups of the silane coupling agent first hydrolyze to generate hydroxyl groups. These hydroxyl groups then undergo a condensation reaction with the hydroxyl groups on the surface of the clay, allowing for organic functional groups to be grafted onto the clay surface. The organic functional groups and polymer matrix react to generate chemical bonds so that the composite material’s interface is more closely combined. Thus, the dispersion of clay in the organic polymer material and the compatibility of the two is better, which improves the flame retardant effect of the composite material. This paper introduces the classification of a silane coupling agent and the mechanism and process of silane coupling agent-modified clay, outlines the mechanism of silane coupling agent-modified clay flame retardant polymers, reviews the research results on flame retardant polymers of various clays after surface treatment with silane coupling agents in recent years, and highlights the synergistic flame retardant effect of clay and flame retardant organized by silane coupling agents. Finally, it is found that the current research in the field of silane coupling agent-modified clay in flame retardants is focused on the modification of montmorillonite, sepiolite, attapulgite, and kaolinite by KH-550, KH-560, and KH-570, and the development trends in this field are also prospected.

In order to study the effect of hydrated phase change materials on the suppression of spontaneous combustion in coal, a thermogravimetric experiment and a reaction activation energy analysis experiment were conducted to explore the changes in the combustion characteristic parameters, characteristic temperature, and activating energy of gas coal, long-flame coal, meagre coal, and lean coal before and after adding hydrated phase change materials. The research results indicated that hydrated phase change materials increased the characteristic temperature point of the coal samples and had effective inhibitory effects on different stages of the oxidation process. However, the effect was best at low temperatures, as hydrated phase change materials undergo phase change and absorb heat when heated at low temperatures, isolating coal from contact with oxygen. The activating energy increased by 1.138–23.048 KJ·mol⁻¹ and the mass loss was reduced by 1.6%–9.3% after inhibition of the coal samples, indicating that the oxidation rate of the various coal samples was slowed down and, thus, spontaneous combustion can be suppressed through the use of hydrated phase change materials. At the same time, this material reduced the combustibility indices of meagre coal and lean coal, as well as the comprehensive combustion indices of long-flame coal and gas coal.