Photovoltaic (PV) modules are highly efficient power generators associated with solar energy. The rapid growth of the PV industry will lead to a sharp increase in the waste generated from PV panels. However, electro-waste can be successfully used as a source of secondary materials. In this study, a unique procedure for recycling PV modules was developed. In the first stage, the aluminum frame and junction box, 18wt%. and 1wt%. of the module, respectively, were removed. The following stage was crucial, involving a mechanical–thermal method to remove the glass, which accounts for 70wt%. As a result, only 11wt%. of the initial mass of the PV was subjected to the next stage of chemical delamination, which reduced the amount of solvent used. Toluene was used to swell the ethylene vinyl acetate, EVA, and allow for the separation of the PV module. The effects of temperature and ultrasound on separation time were investigated. After the separation of silicon cells, metal ribbons, EVA, and the backsheet were obtained. The purity of the polymers was determined by FTIR and elemental analysis. Thermal properties were measured using DSC calorimetry to determine the basic parameters of the material.
4 June 2015 in Journal of the Association for Research in Otolaryngology
In this study, Atomic Force Microscopy-based nanoindentation (AFM-NI) with diamond-like carbon (DLC) coated tip was used to analyze the mechanical response of poly(methyl methacrylate) (PMMA) thin films (thicknesses: 235 and 513 nm) on a silicon substrate. Then, Oliver and Pharr (OP) model was used to calculate hardness and Young’s modulus, while three different Static Linear Solid models were used to fit the creep curve and measure creep compliance, Young’s modulus, and viscosity. Values were compared with each other, and the best-suited method was suggested. The impact of four temperatures below the glass transition temperature and varied indentation depth on the mechanical properties has been analyzed. The results show high sensitivity on experiment parameters and there is a clear difference between thin and thick film. According to the requirements in the nanoimprint lithography (NIL), the ratio of hardness at demolding temperature to viscosity at molding temperature was introduced as a simple parameter for prediction of resist suitability for NIL. Finally, thinner PMMA film was tentatively attributed as more suitable for NIL.
A numerical model is suggested and validated for simulating frictional forces between two samples. The model employs knowledge of surface topographies and values of surface properties provided in the relevant literature and can be applied to contact between complex surfaces. It employs the Lennard-Jones molecular force theory and applies it to a surface segmented into cuboids, which represent separate springs in a Winkler layer. In order to model a contact of two rough surfaces, their asperities are merged into one surface that is put into contact with a perfectly flat surface. Validation, done by atomic force microscopy (AFM), shows that the model can be applied for contacts of rigid samples in the elastic regime of forces.
29 May 2015 in Japanese Journal of Applied Physics
A template release force is one of the important factors for a low-defect template release process in nanoimprint lithography. In this work, the origin of the template release force is investigated by computational study of side wall quality characteristics such as the critical separation forces between the template and the resist interface, and the slope angle of the side wall. The critical separation forces in the normal and shear directions, which are related to adhesion and friction characteristics are experimentally evaluated for the computational study. The computational results show that the shear separation force, which is related to the static friction between the template surface and the resist, strongly affects the release force characteristics. On the other hand, the side wall slope angle also affects the template release force above the critical side wall slope angle. The computational results show good agreement with experimental results.
The tribological characteristics of a below 1 mm micro ball bearing comprising steel disc and cages coated with thin copper and silver films were investigated. Electroplating and laser cutting were used to manufacture used elements. Friction was measured using a linear stage and an adapted version of a friction-loop method. The obtained results show an interesting relationship between the geometric properties of the micro scale thrust bearing and their performance and operational stability, which can be correlated to similar relationships observed in the macro scale. The most optimal design of the bearing showed stable operation, with the simplified rolling resistance coefficient in the range 0.002 to 0.003, independently of applied load, which was in range 150 mN to 1500 mN. The possibility of creating easily manufacturable micro ball bearings with a low rolling resistance coefficient comprised solely of cheap and sturdy elements was shown.