Sustainable ammonia is one of the leading candidates in the search for alternative clean fuels for marine applications. This paper aims to build a simulation model of a six-cylinder, four-stroke diesel engine to investigate the effects of increasing the ammonia proportion in methanol–ammonia fuel blends on engine performance and emissions. In the present study, the conditions of different speeds and different proportions of ammonia in fuel blends are investigated. The results show that the average effective pressure, brake power, and brake torque increase by about 5% with an increased ammonia substitution ratio. In terms of economic performance, the changes under medium and low speed conditions are not obvious. However, the change in high speed conditions is significant. The brake specific fuel consumption (BSFC) is reduced by 6.6%, and the brake thermal efficiency (BTE) is increased by 4%. It is found that the performance of the engine is best at medium speed. The best performance is achieved with higher efficiency and lower emissions. The present results can provide guidance for the optimization of ammonia–methanol blends and their applications in engines.

The combustion of diesel fuel in internal combustion engines faces challenges associated with excessive emissions of pollutants. A direct solution to this issue is the incorporation of cleaner energy sources. In this study, a numerical model was constructed to investigate the characteristics of ammonia–diesel dual-fuel application in a medium-speed diesel engine. Effects of ammonia–diesel blending ratios on engine performance and emissions were investigated. The results indicate that for this engine model, the optimal diesel energy ratio is about 22%. When the diesel energy ratio is less than 22%, the engine’s output performance is significantly affected by the diesel energy ratio, while above 22%, the influence of the intake becomes more pronounced. When the diesel energy ratio is below 16%, the cylinder cannot reach combustion conditions. Diesel energy ratios below 22% can cause ammonia leakage. With increasing diesel energy ratio, the final emissions of carbon oxides increase. With a higher diesel energy ratio, NO emissions become lower. When the diesel fuel energy ratio exceeds 22%, the N₂O emissions can be almost neglected, while below 22%, with poor combustion conditions inside the cylinder, the N₂O emissions will increase.

Ammonia is a promising alternative fuel, which is considered to have the potential to substitute conventional fossil fuels. In the present work, auto-ignition characteristics of ammonia substitution on methane are investigated both experimentally and numerically. The auto-ignition procedure of ammonia-substituted methane/air mixtures are measured behind the reflected shock wave in a shock tube experiment system over temperatures from 1355 to 1877 K, pressure up to 5 atm and an equivalence ratio from 0.5 to 2. Numerical simulation studies using a detailed kinetics mechanism are also performed to gain a deep insight into the auto-ignition procedure of ammonia-substituted methane fuel mixtures. The established numerical model is verified with the measured auto-ignition delay time data by experiments. Then, the auto-ignition delay times are predicted under a wider range of conditions such as equivalence ratio, pressure, temperature, etc. In this way, combustion characteristics of such mixtures are investigated. It is found that adding ammonia fuel to methane will not change the autoignition delay time of methane a lot, while it can effectively benefit the reduction of carbon emissions. Finally, sensitivity analyses are performed to provide essential information for the elementary reaction sensitive to the ignition characteristics. The results present in this work can provide fundamental information for combustion application of ammonia-based fuels.

As a hydrogen-rich and carbon-free fuel, ammonia is regarded as a promising carrier and storage medium for clean energy. By mixing methane with ammonia, the emission of carbon dioxide is also significantly reduced, which is of great significance for reducing greenhouse gas emissions and protecting the environment. However, ignition studies of ammonia/methane mixtures are still limited. In this paper, by means of numerical simulation with detailed chemical reaction mechanism, the effect of ammonia replacing methane on combustion was analyzed. Characteristics of explosion limit under different temperature (750-850K), equivalent ratio (0.5, 1.0 and 2.0) and ammonia mixing ratio (0-90%) were studied. The results show that the explosion limit decreases with the increase of temperature and equivalence ratio. When the proportion of NH3 is around 10%, the explosion limit shows a turning point. When the mole fraction of NH3 is higher than 50%, the explosion limit shows obvious increasing tendency with ammonia addition. Moreover, sensitivity and rate of production were also analyzed to expand the understanding of explosion limit for premixed ammonia-methane fuel blends.