Improving the durability of biological materials is essential for expanding their application areas. In this study, an organic ultraviolet (UV) shielding layer (coating) composed of a UV-curable paint, ethyl acetate, anhydrous alcohol, and an organic UV absorber is constructed on the surface of outdoor bamboo scrimber (OBS). The behaviour of OBS with or without this coating was investigated under accelerated weathering. The physical properties photostability of the samples before and during exposure were evaluated by characterizing the colour and glossiness. Contact angle (CA) measurements and surface free energy (SFE) calculations were performed to investigate the wettability of the coatings. Attenuated total reflectance Fourier transform infrared spectroscopy was used to characterize the changes in the functional groups of the coatings during weathering. The experimental results have shown that the colour, glossiness, CA, SFE, and functional groups photostability of the sample with the UV shielding coating increased significantly compared to those of the control sample. The coating with 5% organic UV absorber was considered as the best UV shielding layer in this study, as it successfully protected the OBS and reduced the surface photodegradation of the substrate and the coating itself.

A facile method to synthesize ZnO-TiO₂-layered double-nanostructures with the average thickness of 20 μm on a bamboo substrate was proposed to improve the antifungal and flame-retardant properties. The cross-linked wurtzite ZnO nanostructures with an average thickness of approximately 0.14 μm were uniformly distributed on the anatase TiO₂ surface. The energy-dispersive X-ray spectroscopy (EDS) confirmed that the ZnO-TiO₂ coating on bamboo was a layered double nanostructure. During a two-month antifungal test conducted in an outdoor environment, the fungi began to grow after one week on pristine bamboo and three weeks on ZnO-bamboo and TiO₂-bamboo. Furthermore, there was an infected area of 100% after four weeks for pristine bamboo and six weeks for ZnO-bamboo, while there was an infected area of 43% after eight weeks for TiO₂-bamboo. By comparison, there was no visible fungal growth on ZnO-TiO₂-bamboo until the end of the test. The electron spin resonance (ESR) technique has demonstrated that the reactive oxygen species (ROS) of •O₂⁻ and •OH were produced from the ZnO-TiO₂ surface under visible light irradiation (λ > 420 nm). This large quantity of •O₂⁻ compared to •OH is considered to be mainly responsible for the inactivation of fungi. Additionally, the limiting oxygen index has increased from 25.6% to 30.2% after being covered with a ZnO-TiO₂ coating, which revealed a significant enhancement of its flame-retardant property.

Heat treatment is an excellent method of improving the properties of wood. Study of the physical and chemical changes of lignin during heat treatment is essential for expanding the application areas based on new properties. In this study, we investigated the degradation behavior of enzymatic hydrolysis lignin (EHL) heat treated at different temperatures (180 °C, 200 °C, and 220 °C) and for different durations (2 h and 4 h). The optical property changes of EHL before and after heat treatment were investigated by measuring color and UV-Vis absorbance changes. Fourier transform infrared spectroscopy (FTIR) was used to characterize the chemical modifications resulting from heat treatment. Mass spectrometry (MS) was used to elucidate the variation of the mass-to-charge (m/z) ratios of ions produced by EHL during heat treatment. These experimental results indicate that both the EHL mass loss percentages and chromatic aberration exhibited an increase with increasing temperature and duration of heat treatment. In contrast, the UV-Vis absorbance, most of the FTIR absorption peaks, and the m/z values of EHL showed a decreasing trend. It was found that the color change of lignin was not the major cause of wood discoloration during heat treatment. The better resistance of the heat treated wood toward solar radiation was attributed to the lower UV absorption of post-treatment lignin.

Wood-fiber-mat-reinforced composites (WFMRCs) possess excellent physical and mechanical properties and provide high structural performance, making them a suitable engineering structural material. However, WFMRCs are susceptible to biological attack by fungi and insects when they are used in outdoor environments. In this study, the efficacy of copper triazole (CuAz) preservative treatment in protecting WFMRC against decay by white- and brown-rot fungi (Trametes versicolor and Gloeophyllum trabeum, respectively) was evaluated. Both fungi caused a mass loss in the untreated scrimber of more than 15%, while the CuAz preservative treatment reduced the mass loss to 5%. The measurement results show that CuAz treatment could effectively reduce the degradation rate of three major components of wood; inhibit fungal colonization and degradation; and improve the decay resistance of WFMRC. The atmospheric impregnation of CuAz preservative is more suitable for the material features of WFMRC than vacuum impregnation and can be considered for practical industrial applications. This study provides technical support for the protection and outdoor application of WFMRCs.

The effect of ultraviolet radiation on the surface deterioration of scrimber composites with different densities and levels of resin content was investigated for this paper. The surface color, gloss, roughness, and wettability of the samples were investigated to determine the extent of surface changes due to accelerated ageing. The results indicated that all scrimber composites exhibited variation in the color of their surfaces during artificial xenon light exposure. After artificial accelerated ageing, the surface contact angle and roughness were found to increase, whereas the surface gloss and surface free energy decreased. Furthermore, it was observed that the density and resin content of the scrimber composites contributed to reductions in their color variation, wettability, and roughness during weathering, which suggested that the density and resin content played important roles in determining their surface photodegradation properties. Artificial ageing resulted in the degradation of lignin and hemicellulose, thus causing severe surface characteristics.

Bamboo cracking is primarily attributed to the influence of moisture on its structure. Natural-speckle digital image correlation (DIC) was employed to characterize tangential shrinkage in cross-sections, using parenchyma cells as intrinsic speckle patterns. Shrinkage behavior during the 24 h drying process at a temperature of 103 °C across the external, middle, and internal layers was comparatively analyzed in bamboo nodal regions (NR), internodal regions (IR), and transitional zones (TZ, i.e., node–internode interfaces). Moisture had the most pronounced effect on NR, which consistently exhibited the highest moisture content and shrinkage ratios during the drying process. Notably, the drying shrinkage of the external layer was significantly greater than that of other layers. Specifically, the drying shrinkage strain ratio of the external layer of NR is 3.02 times higher than that of the internal layer, while for IR, it is 3.60 times higher. Furthermore, the external layer of NR exhibits substantial deformation during the initial stages of drying, with a drying shrinkage strain ratio of 5.96% for 2 h. The results demonstrated that shrinkage deformation in bamboo nodes was significantly greater than in other regions, offering valuable insights for developing strategies to mitigate bamboo cracking.