In electrochemical devices, such as batteries, traditional electric double layer (EDL) theory holds that cations in the cathode/electrolyte interface will be repelled during charging, leaving a large amount of free solvents. This promotes the continuous anodic decomposition of the electrolyte, leading to a limited operation voltage and cycle life of the devices. In this work, we design a new EDL structure with adaptive and passivating properties. It is enabled by adding functional anionic additives in the electrolyte, which can selectively bind with cations and free solvents, forming unique cation-rich and branch-chain like supramolecular polymer structures with high electrochemical stability in the EDL inner layer. Due to this design, the anodic decomposition of ether-based electrolytes is significantly suppressed in the high voltage cathodes and the battery shows outstanding performances such as super-fast charging/discharging and ultra-low temperature applications, which is extremely hard in conventional electrolyte design principle. This unconventional EDL structure breaks the inherent perception of the classical EDL rearrangement mechanism and greatly improve electrochemical performances of the device.

The application of membrane electrode assemblies is considered a promising approach for increasing the energy efficiency of conventional alkaline water electrolysis. However, previous investigations have mostly focused on improving membrane conductivity and electrocatalyst activity. This study reports an all-in-one membrane electrode assembly obtained by de novo design. The introduction of a porous membrane readily enables the oriented intergrowth of ordered catalyst layers using solvothermal methods, leading to the formation of an all-in-one MEA for alkaline water electrolysis. This all-in-one MEA features ordered catalyst layers with large surface areas, a low-tortuosity pore structure, integrated catalyst layer/membrane interfaces, and a well-ordered OH^- transfer channel. Owing to this design, a high current density of 1000 mA cm⁻² is obtained at 1.57 V in 30 wt% KOH, resulting in a 94% energy efficiency. This work highlights the prospects of all-in-one membrane electrode assemblies in designing next-generation high-performance alkaline water electrolysis.

Solid polymer electrolytes suffer from the polymer-dominated Li ⁺ solvation structure, causing unstable electrolyte/electrode interphases and deteriorated battery performance. Here, we design a class of selectively fluorinated aromatic lithium salts (SFALS) as single conducting lithium salts to regulate the solvation structure and interfacial chemistry for all-solid-state lithium metal batteries. By tuning the anionic structure, the Li ⁺ -polyether coupling is weakened, and the Li ⁺ -anion coordination is enhanced. The hydrogen bonding between the SFALS and polymer matrix induces a special “triad”-type solvation structure, which improves the electrolyte homogeneity and mechanical strength, and promotes the formation of an ultrathin and robust Li ₂ O-rich solid electrolyte interphase. Therefore, the stable cycling of more than 1650 cycles (Coulombic efficiency, 99.8%) for LiFePO ₄ /Li half cells and 580 cycles (97.4% capacity retention) for full cells is achieved. This molecular engineering strategy could inspire further advancements of functional lithium salts for practical application of all-solid-state lithium metal batteries.

Since the discovery of innovative two-dimensional (2D) materials, significant efforts have been dedicated to exploring their intriguing properties and emerging applications. Among all candidates, transition metal dichalcogenides (TMDs) have proven to be exceptional for gas sensing, while defects engineering has been introduced to modify the pristine TMDs for better gas sensing performances. In this review, we systematically summarize types of defects, advanced characterization techniques, and state-of-the-art controllable synthetic methods. Various types of defects in TMDs can induce diverse changes in chemical and electron structures, which are closely correlated with gas sensing ability. Therefore, connections between defects and gas sensing mechanisms and performances have been addressed based on both defect categories and electron affinity of gases. This review will be a guide for researchers in defective materials and open up the field of precisely synthesis chemistry and deepen the understanding of the underlying effects of defects in other 2D materials.

During the global energy transition, electric vehicles and electrochemical energy storage systems are rapidly gaining popularity, leading to a strong demand for lithium battery technology with high energy density and long lifespan. This technological advancement, however, hinges critically on resolving safety challenges posed by intrinsically reactive components particularly flammable polymeric separators, organic electrolyte systems, and high-capacity electrodes, which collectively elevate risks of thermal runaway (TR) under operational conditions. The strategic integration of smart polymeric materials that enable early detection of TR precursors (e.g., gas evolution, thermal spikes, voltage anomalies) and autonomously interrupt TR propagation chains has emerged as a vital paradigm for next-generation battery safety engineering. This paper begins with the development characteristics of thermal runaway in lithium batteries and analyzes recent breakthroughs in polymer-centric component design, multi-parameter sensing polymers, and TR propagation barriers. The discussion extends to intelligent material systems for emerging battery chemistries (e.g., solid-state, lithium-metal) and extreme operational environments, proposing design frameworks that leverage polymer multifunctionality for hierarchical safety mechanisms. These insights establish foundational principles for developing polymer-integrated lithium batteries that harmonize high energy density with intrinsic safety, addressing critical needs in sustainable energy infrastructure.