Conventionally used brass alloy CuZn30 shows problems with corrosion resistance in the form of dezincification when used in brass instruments. Therefore, within the scope of this investigation, a new brass alloy CuZn30 is developed in the microalloy range with corrosion-free or corrosion-inhibiting properties. First, the influence of microalloying elements on the phase composition is investigated by simulation using Thermo-Calc. On the basis of this, suitable alloying elements and contents are selected and a modified CuZn30X alloy with 0.1% phosphorus, tin, and nickel in mass fractions, respectively, is produced. The modified alloy is then investigated with regard to its mechanical and microstructural composition and its corrosion properties. The corrosion properties were examined using stress corrosion cracking tests, dezincification tests, and the recording of polarization curves. The modified alloy exhibited good cold and hot rolling properties as well as good corrosion resistance. The dezincification test confirmed the improved corrosion resistance of the modified CuZn30X alloy, which is attributed to the formation of a protective top layer due to the alloying elements.
In this work, the microstructural deformation and damage mechanisms of TRIP steel metal matrix composites (MMCs) reinforced with Magnesia Partially Stabilized Zirconia (Mg-PSZ) particles are investigated by employing in situ tensile testing within a scanning electron microscope chamber, complemented by digital image correlation and advanced image processing techniques. The study is carried out on samples with varied volume fractions (0%, 10%, and 20%) of zirconia particles and damage mechanisms in different samples under specified loading conditions. Through both qualitative and quantitative assessments of deformation, damage, and clustering, the investigation provides a comprehensive understanding of the distribution and damage initiation. The study findings reveal that, generally, the steel matrix exhibits high toughness, with minimal occurrences of microcracking at high strains that cause significant damage. In samples with increasing particle content, delamination at the matrix–particle interface and cracking of Mg-PSZ particles were found to be critical contributors to material failure and were quantitatively analyzed using computational analyses conducted with MATLAB. The work highlights the initiation and evolution of each damage mechanism in zirconia particle-reinforced TRIP steel MMCs to facilitate scientists and engineers in improving manufacturing and application decisions in industries such as automotive, aerospace, and heavy machinery, which demand materials with exceptional toughness and durability. Graphical Abstract
Due to their low density and high specific strength, magnesium alloys offer great potential as a design material for lightweight construction. An economical and energy-efficient method for the production of magnesium wire is the technology of twin-roll casting. In this work, the deformation behaviour of twin-roll cast and heat-treated AZ31 wire pre-profile is investigated for the first time during the compression test at different temperatures (250–400 °C) and forming speeds (0.01–10 s−1). To obtain optimal parameters, a processing map is created, and the microstructural changes during the hot forming processes are determined by accompanying microstructure characterization through an optical microscope and scanning electron microscope. The heat treatment causes a reduction in segregation and a homogeneous microstructure. The average activating energy for plastic deformation of twin-roll cast and heat-treated magnesium alloy AZ31 is 159.008 . The instability region of the process map starts at a forming temperature of 250 °C and extends into the range of high forming speeds (1–10 s−1). In this area, cracks in the microstructure can be detected during hot forming. At high temperatures (300–350 °C), dynamic recrystallization at the grain boundaries is observed as the main forming mechanism. Based on these results and observations, existing models for describing the hot forming behaviour of magnesium alloys can be extended and validated.