Studying the effect of functional groups on the porosity structure and adsorption efficiency of polymer materials is becoming increasingly interesting. In this work, a novel porous polyaminal-linked polymer, based on naphthalene and melamine (PAN-NA) building blocks, was successfully synthesized by a one-pot polycondensation method, and used as an adsorbent for both CO₂ and heavy metals. Fourier transform infrared spectroscopy, solid-state ¹³ C NMR, powder X-ray diffraction, and thermogravimetry were used to characterize the prepared polymer. The porous material structure was established by field-emission scanning electron microscope and N₂ adsorption–desorption methods at 77 K. The polymer exhibited excellent uptake of CO₂, 133 mg/g at 273 K and 1 bar. In addition, the adsorption behavior of PAN-NA for different metal cations, including Pb(II), Cr(III), Cu(II), Cd(II), Ni(II), and Ba(II), was investigated; a significant adsorption selectivity toward the Pb(II) cation was detected. The influence of pH, adsorbent dose, initial concentrations, and contact time was also assessed. Our results prove that the introduction of naphthalene in the polymer network improves the porosity and, thus, CO₂ adsorption, as well as the adsorption of heavy metals.

In this work, palladium nanoparticles, supported by polyaminals (Pd@PAN-NA), were synthesized via a reverse double solvent approach and used as a nano catalyst. The thermogravimetric and the elemental analysis revealed that the catalyst had good dispersity and improved thermal stability. The catalytic activity of the prepared Pd@PAN-NA catalyst was studied for a methylene blue chemical reaction in the presence of NaBH₄ as a reducing agent. The effect of the catalyst dose, pH, and dye initial concentration were examined to optimize the chemical reduction conditions. The prepared catalyst Pd@PAN-NA removed 99.8% of methylene blue organic dye, indicating its potential effect for treating waste and contaminated water.

The response to the high demand for decreasing the amount of CO₂ in the atmosphere, a new polyaminal-based polymer network was designed and successfully prepared through one-pot polycondensation reaction of melamine and [2,2′-Bipyridine]-5,5′-dicarbaldehyde. The formation of the polymer structure was confirmed by FT-IR, solid-state ¹³C NMR, and powder-X-ray diffraction. The porous properties of the polymeric structure were confirmed by field-emission scanning electron microscope and N₂ adsorption–desorption methods at 77 K. The prepared polymer can take up 1.02 mmol/g and 0.71 mmol/g CO₂ at 273 K and 298 K, respectively, despite its relatively modest Brunauer–Emmett–Teller (BET) surface area (160.7 m²/g), due to the existence of superabundant polar groups on the pore surfaces.