Agro-industrial waste valorization is an attractive approach that offers new alternatives to deal with shrinkage and residue problems. One of these approaches is the synthesis of advanced carbon materials. Current research has shown that citrus waste, mainly orange peel, can be a precursor for the synthesis of high-quality carbon materials for chemical adsorption and energy storage applications. A recent approach to the utilization of advanced carbon materials based on lignocellulosic biomass is their use in solar absorber coatings for solar-thermal applications. This study focused on the production of biochar from Citrus aurantium orange peel by a pyrolysis process at different temperatures. Biochars were characterized by SEM, elemental analysis, TGA-DSC, FTIR, DRX, Raman, and XPS spectroscopies. Optical properties such as diffuse reflectance in the UV−VIS−NIR region was also determined. Physical-chemical characterization revealed that the pyrolysis temperature had a negative effect in yield of biochars, whereas biochars with a higher carbon content, aromaticity, thermal stability, and structural order were produced as the temperature increased. Diffuse reflectance measurements revealed that it is possible to reduce the reflectance of the material by controlling its pyrolysis temperature, producing a material with physicochemical and optical properties that could be attractive for use as a pigment in solar absorber coatings.

Compound parabolic concentrators are relevant systems used in solar thermal technology. With adequate tailoring, they can be used as an efficient and low-cost alternative in residential water heating applications. This work presents a simulation study using a ray tracing analysis. With this technique, we simulate the interaction between solar rays and solar concentrator to quantify the amount of energy that impinges on the receiver at a particular time. Energy availability is evaluated in a comparison of two configurations throughout the year: static setup at 21° and multi-position setup; tilted with respect to the horizontal, depending on three seasonal positions: 0° for summer, 16° for spring/autumn, and 32° for winter, with the aim to evaluate the amount of available energy in each season. The fact that a tracking system can be dispensed with also represents an economical option for the proposed application. The results showed that at 21°, the proposed solar Compound Parabolic Concentrator (CPC) works satisfactorily; however, by carrying out the selected angular adjustments, the overall energy availability increased by 22%, resulting in a more efficient option. The most effective design was also built and analyzed outdoors. The obtained thermal efficiency was of ~43%. The optical design and its evaluation developed herein proved to be a valuable tool for prototype design and performance evaluation.

This study presents the optical improvement of a high flux solar simulator (HFSS) with controllable flux-spot capabilities developed for researching solar thermal and thermochemical processes. The HFSS is comprised of seven $2.5{\mathrm{kW}}_{\mathrm{el}}$ Xenon arc lamps coupled with ellipsoidal reflectors, a servo-controlled attenuator curtain, and three-axes linear test bench. Different attenuators were designed and tested in order to identify the best curtain geometry to improve the HFSS modulation with the lowest possible radiative losses. The optical design improvement was performed with the aid of TracePro, a Monte Carlo ray-tracing software. From simulation results, radiative peak flux from 1700 to $480{\mathrm{kWm}}^{-2}$ from the focal plane to 300 mm further back was estimated without curtains. By using the attenuators, flux levels from 1570 to $92{\mathrm{kWm}}^{-2}$ at the focal plane were also estimated. An experimental validation was achieved with a single lamp-reflector unit obtaining peak flux distributions from $200\pm 20{\mathrm{kWm}}^{-2}$ to $97\pm 9.7{\mathrm{kWm}}^{-2}$ from the focal plane to 300 mm behind. Flux modulation from 170 to $1.5{\mathrm{kWm}}^{-2}$ was also measured at the focal plane using a servo-controlled curtain from fully-open slats (0°) to partially closed (60°). With this attenuator, introduced as the shutter of the system, the use of several lamps or electronic rectifiers is avoided and the radiative flux is modulated with high resolution in an optomechatronical form.

Solar resource assessment is fundamental to reduce the risk in selecting the solar power-plants’ location; also for designing the appropriate solar-energy conversion technology and operating new sources of solar-power generation. Having a reliable methodology for solar irradiance forecasting allows accurately identifying variations in the plant energy production and, as a consequence, determining improvements in energy supply strategies. A new trend for solar resource assessment is based on the analysis of the sky dynamics by processing a set of images of the sky dome. In this paper, a methodology for processing the sky dome images to obtain the position of the Sun is presented; this parameter is relevant to compute the solar irradiance implemented in solar resource assessment. This methodology is based on the implementation of several techniques in order to achieve a combined, fast, and robust detection system for the Sun position regardless of the conditions of the sky, which is a complex task due to the variability of the sky dynamics. Identifying the correct position of the Sun is a critical parameter to project whether, in the presence of clouds, the occlusion of the Sun is occurring, which is essential in short-term solar resource assessment, the so-called irradiance nowcasting. The experimental results confirm that the proposed methodology performs well in the detection of the position of the Sun not only in a clear-sky day, but also in a cloudy one. The proposed methodology is also a reliable tool to cover the dynamics of the sky.