Surface modification of polyimides (PIs) using electrospinning would significantly improve the performance of TENGs because of the larger surface area of the electrospun friction layer. However, PIs generally have high solvent resistance, so it is complicated to convert them into nanofibers using electrospinning process. This study aims to fabricate PI nanofibers via simple, one-step electrospinning and utilize them as a friction layer of TENGs for better performance. PI nanofibers were directly electrospun from PI ink made of polyimide powder without any additional process. The effect of PI concentration on spinnability was investigated. Uniform and continuous nanofibrous structures were successfully produced at concentrations of 15 wt% and 20 wt%. Electrospun PI nanofibers were then utilized as a friction layer for TENGs. A TENG with 20 wt% produced an open circuit voltage of 753 V and a short circuit current of 10.79 μA and showed a power density of 2.61 W m⁻² at a 100 MΩ load resistance. During tapping experiment of 10,000 cycles, the TENG could stably harvest electrical energy. The harvested energy from the proposed TENG is sufficient to illuminate more than 55 LEDs and drive small electronic devices, and the TENGs exhibit excellent performance as a wearable energy harvester.

Even though porous elastomers and elastomeric nanocomposites have shown many advantages for triboelectric nanogenerators (TENGs), their fabrication techniques are relatively complicated, inefficient, and time-consuming. In this work, we introduced a simple, efficient and rapid concept to fabricate porous polydimethylsiloxane (PDMS) nanocomposites. PDMS nanocomposites with various porous structure were produced within a few minutes through just one-step microwave irradiation without any post-processing. Three solvents with different boiling points were selected as sacrificial materials to control porous structure. To fabricate nanocomposites, BaTiO₃ (BT) nanoparticles were mixed into the uncured PDMS and sacrificial solvent mixture. Additionally, Ni nanoparticles were also used to understand the effect of embedded material’s property on porous structure. The porous BT/PDMS nanocomposites fabricated via microwave irradiation greatly enhanced the electrical performance of TENGs as compared to a pure solid elastomer. The present study provides a simple, rapid and inexpensive approach for fabricating TENGs based on porous elastomeric nanocomposites.

Paper and pencil have many advantages in triboelectric nanogenerators (TENGs) in terms of low-cost, light weight, and environment friendliness. In this work, a pencil-on-paper triboelectric nanogenerator (PP-TENG) with highly enhanced performance was introduced. In order to use paper as a friction layer and improve its triboelectric performance, a simple and rapid paper-coating process was utilized with polyvinylidene fluoride (PVDF), polyvinyledenedifluoride-trifluoroethylene (PVDF-TrFE), and poly(methyl methacrylate) (PMMA) solutions. The fabrication process of the PP-TENG was completed within 10 minutes via pencil drawing of an electrode followed by a solution coating. With an optimized electrode shape, the PP-TENG showed a maximum power density of 64 mW m⁻², which is more than 19 times higher than that of the uncoated paper TENG. The electrical performance of the PP-TENG was sufficient to drive a few hundred LEDs and charge various capacitors. It was maintained after the paper was folded or even crumpled. The proposed PP-TENG is expected to be utilized with other wearable electronic devices.