The microstructure, mechanical performance, and tribological properties of SiC ceramic coatings prepared via atmospheric plasma spraying (APS) and chemical vapor deposition (CVD) method were compared to provide good anti-wear protection for carbon/carbon composites. The surface morphology of the APS-SiC coating was characterized as having a porous structure, whilst the CVD-SiC coating presented with many pyramidal-shaped crystals constituting the surface. The APS-SiC coating consists of a dominating SiC phase and a small fraction of the Si phase, while the XRD pattern of the CVD-SiC coating mainly consists of the SiC phase. The dense crystalline microstructure of the CVD-SiC coating made it possess a higher hardness and Young’s modulus at 31.0 GPa and 275 GPa, respectively. The higher H/E and H³/E² parameters of the CVD-SiC coating implied that it exhibited better plastic resistance, which is also beneficial for anti-wear properties. The scratch test reflected the critical loads of the spallation of the APS-SiC coating and CVD-SiC coating, which were evaluated to be 25.9 N and 36.4 N, respectively. In the tribological test, the friction coefficient of the APS-SiC coating showed obvious fluctuations at high load due to damage to the SiC coating. The wear mechanism of the APS-SiC coating was dominated by abrasive wear and fatigue wear, while CVD-SiC was mainly dominated by abrasive wear. The wear rate of the CVD-SiC coating was far below that of the APS-SiC coating, suggesting the better wear-resistance of the CVD-SiC coating.