MXene, an advanced family of 2D ceramic material resembling graphene, has had a considerable impact on the field of research because of its unique physiochemical properties. MXene has been synthesized by the selective etching of MAX via different techniques. However, with the passage of time, due to the need for further progress and improvement in MXene materials, ideas have turned toward composite fabrication, which has aided boosting the MXene composites regarding their properties and applications in various areas. Many review papers are published on MXene and their composites with polymer, carbon nanotube, graphene, other carbon, metal oxides and sulfides, etc., except metal composite, and such papers discuss these composites thoroughly. In this review article, we illustrate and explain the development of MXene-based metal composites. Furthermore, we highlight the synthesis techniques utilized for the preparation of MXene composites with metal. We briefly discuss the enhancement of properties of the composites and a wide range of applications as an electrode substance for energy storage devices, electrochemical cells, supercapacitors, and catalytic and anti-corrosive performance. Major obstacles in MXene and metal composite are mentioned and provide future recommendations. Together, they can overcome problems and enable MXene and composites on commercial-scale production.
18 June 2019 in International Journal of Applied Ceramic Technology
In this study, the prestressed coating reinforcement method was employed to create kyanite-coated zirconia toughened alumina (ZTA) prestressed ceramics. Due to the mismatch of the coefficient of thermal expansion (CTE) between the coating and substrate, compressive residual stress was introduced in the coating. The effects of compressive residual stress on the mechanical properties of ZTA have been demonstrated. Results show that the flexural strength of the kyanite-coated ZTA ceramics improved by 40% at room temperature compared to ZTA ceramics. In addition, the temperature dependence of mechanical properties has also been discussed. And the results show that the reinforcement gradually diminished with increasing temperature and eventually disappeared at 1000 °C. The modulus of elasticity of the material also exhibits a decreasing trend. Furthermore, the introduction of the prestressing coating enhanced the thermal shock resistance, but the strengthening effect diminished as the temperature increased and completely disappeared at 800 °C.
In this work, the rapid thermal shock behavior of Ti2AlC ceramics was studied using induction heating. The present evaluation method possesses the merits of very rapid heating within tens of seconds and fast quenching in water of less than 0.1 s, removing the shortcomings of traditional thermal shock. For comparison, the samples were also quenched in the air to investigate the thermal shock mechanisms. The results showed that the abnormal shock occurred in the samples when quenching in water, ascribed to the formed oxide layer on the surface of Ti2AlC ceramic inhibited the water penetration into the substrate. The quenched Ti2AlC samples still had a high residual flexural strength above 167 MPa up to 1150 °C, exhibiting promising applications in the high-temperature fields.
In order to broaden the selectivity of graphite nanosheet additives on epoxy resin-based coatings and verify the size effect, this work aims to dope graphite nanosheets of different sizes into the three-dimensional structure produced by cross-linking and curing epoxy resin and polyamide resin. In addition, a micro-nano level secondary structure and a surface with special roughness are constructed to obtain the composite epoxy hydrophobic coating. The influence of the size effect of graphite nanosheets on the hydrophobic performance and corrosion resistance of the coating is summarized as well. Among them, the optimized doping size (2.2 μm) of graphite nanosheets in the epoxy coating showed the largest impedance arc of 2.58 × 108 Ω cm2, which could form an excellent nano-network covering the micropores to impede the diffusion of corrosive medium. Through simulation calculation analysis, we also found that the edge site of graphene is more effective in capturing H2O and O2; therefore, a smaller size of graphene with a large edge can be more favorable. This work will be used as a reference for the industrial application of graphite anti-corrosive coating.