This experimental research aimed to examine potential production and utilization of RDF derived from mixed municipal solid waste using bio-drying technology to be used as a substitute fuel for the traditional fuel currently used in cement plants in Jordan. The characteristics of RDF produced were identified and compared with limits and criteria set by some European countries. An economic model for RDF utilization in cement industry was created. The model proposes six different options resulting from adding RDF as a substitute fuel for the petcoke fuel currently used. A cost analysis for each option proposed was performed to estimate the economic and environmental savings of RDF utilization in cement industry. At the end of the bio-drying process, the mass of dried waste directed to the landfill was reduced by about 35%. In the case of the recovery of RDF materials from dried waste, the mass of waste to be landfilled was reduced by 69%. The bio-drying process allowed an increase in the heating value of waste (LHV) by 58% to reach 15.58 MJ/kg, as a result of the reduction of waste moisture. RDF produced had high calorific value, low water content, and satisfactory chlorine content. With regard to the concentration of the heavy metals, all of the RDF samples tested had lower concentrations than those values set by some European countries. The findings showed that adding 15% RDF as a substitute fuel, equaling 4.92 tons/h, to the fuel used in cement kilns will save 486 USD/h in petcoke costs, with 2.27 tons/h of CO₂ being emitted into the atmosphere at a net saving of 389 USD/h.

Hydrogen produced from chlor-alkali plants in Jordan is typically wasted and vented to the atmosphere. If it is recovered and utilized then it can viably play a significant role for process heat on site. This study demonstrates how cleaner production can be applied to the chlor-alkali industry, with focus on utilization of hydrogen as energy resource. A chlor-alkali based on membrane cell process, in northern part of Jordan, was examined as a case of reusing excess hydrogen produced. In the baseline scenario, 47% of produced hydrogen was used in HCl production, 10% in controlling pressure difference, and the remainder was not used (i.e. 43% of hydrogen was vented into the atmosphere). The proposed cleaner production option was to install a hydrogen boiler next to the existing fuel boiler and utilize the hydrogen to generate steam for on-site process heating purposes. The effectiveness of this cleaner production option was discussed in relation to its technical and environmental feasibility. On-site utilization of hydrogen was found to provide 34% of the total steam needed at the full capacity. This in return yields a saving percentage of around 33.37% and a payback period of 0.947 year. From environmental perspective, theoretically, carbon dioxide emission reductions can be up to 1810 tons based on the chlor-alkali productions pattern for 24 consecutive months.