The scarcity of potable water emphasizes the urgent need to develop and implement more sustainable treatment technologies, considering both energy consumption and environmental impact. These technologies require effective disinfection systems that avoid the use of chemicals. Innovations in this area, utilizing UV-LED technology, can significantly improve efficiency, reduce costs, and mitigate environmental impacts. This study aimed to evaluate the antimicrobial properties of various encapsulated UV light-emitting diodes (LEDs) to identify the most suitable candidate for constructing an LED array capable of disinfecting large volumes of water. Different devices from various manufacturers, with differing costs and wavelengths, were examined, leading to the selection of the optimal candidate (LED 2) based on its antimicrobial effectiveness and cost-effectiveness. The impact of parameters such as bacterial concentration, sample volume, exposure time, and conditions on disinfection capacity was thoroughly investigated. Exposure to LED 2 resulted in substantial reductions in the viability of bacteria and yeast, demonstrating efficacy even against Clostridium perfringens endospores. Subsequently, an LED array was developed based on these findings and rigorously evaluated for efficacy, confirming its effectiveness as an efficient and environmentally friendly water treatment device.
In this work, silicon oxide based coatings with embedded graphene nanoplatelets (content ranging from 1.8 wt.% to 7.2 wt.%) have been developed following the sol-gel route, using AISI430 stainless steel as substrate and dip and roll-to-roll as coating techniques. The tribological and corrosion behaviour of these coatings have been evaluated and compared to bare steel. Concerning tribological behaviour, the coefficient of friction and wear print were significantly reduced with increasing the graphene nanoplatelets content. Regarding corrosion, all coatings showed improved corrosion behaviour compared to bare steel. However, higher concentration of nanoplatelets revealed a negative effect on the corrosion resistance, probably due to aggregation. Taking into account these two counteracting effects, as final part of this work, a bilayer coating with different graphene content has been proposed and fabricated. A top layer, with high graphene nanoplatelets concentration has allowed enhanced tribological properties whereas bottom layer, with no graphene nanoplatelets assures corrosion inhibition under harsh environments.