The formation mechanism of TiC particles in a Ni-Ti-C system were revealed by using differential thermal analysis (DTA), XRD, and SEM to identify the reaction products in different temperature ranges. The results indicated that the synthesis mechanism of TiC in Ni-Ti-C system was complex; several reactions were involved in the combustion synthesis of TiC-Ni composite. The Ni-Ti intermediate phases play important roles during the formation of TiC. Moreover, the influence of heating rate on the size range of TiC was also discussed.

In this work, the microstructure and solidification behavior of nickel-based superalloy GTD222 at different cooling rates are studied. The solidification of the superalloy GTD222 proceeds as follows: L → L + γ, L → L + γ + MC, L → L + (γ/γ′)-Eutectic and L → η phase. Due to alloying element redistribution, the temperature of the solidus GTD222 superalloy, 1310 °C, is slightly lower than the temperature of the liquidus, which is 1360 °C. It was found that the dendrite arm spacing of the alloy decreased with the increase of the cooling rate from 200 μm at 2.5 K/min to 100 μm at 20 K/min.