Ammonia is considered to be a potential medium for hydrogen storage, facilitating CO2-free energy systems in the future. Its high volumetric hydrogen density, low storage pressure and stability for long-term storage are among the beneficial characteristics of ammonia for hydrogen storage. Furthermore, ammonia is also considered safe due to its high auto ignition temperature, low condensation pressure and lower gas density than air. Ammonia can be produced from many different types of primary energy sources, including renewables, fossil fuels and surplus energy (especially surplus electricity from the grid). In the utilization site, the energy from ammonia can be harvested directly as fuel or initially decomposed to hydrogen for many options of hydrogen utilization. This review describes several potential technologies, in current conditions and in the future, for ammonia production, storage and utilization. Ammonia production includes the currently adopted Haber–Bosch, electrochemical and thermochemical cycle processes. Furthermore, in this study, the utilization of ammonia is focused mainly on the possible direct utilization of ammonia due to its higher total energy efficiency, covering the internal combustion engine, combustion for gas turbines and the direct ammonia fuel cell. Ammonia decomposition is also described, in order to give a glance at its progress and problems. Finally, challenges and recommendations are also given toward the further development of the utilization of ammonia for hydrogen storage.
Heat transfer augmentation of turbulent single-phase flow in a concentric tube heat exchanger with short-length twisted tape inserts was numerically examined herein. The twisted tape length ratios were 0.25, 0.5, 0.75, and 1.0. The twisted tape was comprised of an aluminum strip with a constant thickness, a pitch, and a width of 0.7, 35, and 12.6 mm, respectively. This study was conducted for heat exchangers with/without twisted tape inserts. The Reynolds numbers ranging from 4,500 to 18,500 were applied. The analyses showed an improvement in heat transfer and friction factor in each of the tube systems, and the results were used to determine the system that delivered the best performance. The correlations of Gnielinski and Petukhov were also used for validating the predicted Nusselt number and friction factor for the plain tube. The results indicated that heat transfer augmentation was elevated as the tape-length ratio increased. The respective highest average Nusselt number and friction factor obtained in this study were 0.51 and 2.84 times greater than that of the plain tube.
In this study, a numerical simulation has been conducted in order to evaluate the thermal hydraulic performance of a turbulent single-phase flow inside an enhanced tube equipped with a square-cut twisted tape (STT) insert. The classical twisted tape (CTT) insert was also investigated for comparison. The k-ε renormalized group turbulence model has been utilized as the turbulent model. Various twist ratios (y/W) of 2.7, 4.5, and 6.5 were investigated for the Reynolds number range of 8000–18,000, with water as the working fluid. The numerical results indicated that, in comparison with the plain tube (PT), the tube equipped with the STT with the twist ratios of 2.7, 4.5, and 6.5 led to an increase in the values of the Nusselt number and friction factor in the inner tube by 45.4–80.7% and 2.0–3.3 times, respectively; in addition, the highest thermal performance of 1.23 has been obtained. The results further indicated that the tube equipped with the CTT of the same twist ratios improved the Nusselt number and friction factor in the inner tube by 40.3–74.4% and 1.7–3.0 times, respectively, in comparison with the PT; further, the maximum thermal performance of 1.18 was achieved.
Titania-based nanofluid flowing inside a circular tube under the boundary condition of a horizontal uniformly heated wall was investigated numerically for both laminar and turbulent flows. In this work, an innovative numerical method using an Eulerian approach for the two-phase mixture model was used to simulate the flow and convective heat transfer characteristics. The effect of nanoparticle loading and Reynolds number on the flow and heat transfer characteristics was observed. The Reynolds number was 500 and 1200 for laminar flow, while for turbulent flow, the Reynolds number was varied in the range from 4000 to 14,000. A comparison with the established empirical correlations was made. The results clearly showed at the laminar and turbulent flows that the existing nanoparticles provided a considerable enhancement in the convective heat transfer. For laminar flow, the numerical results found that the enhancement in the convective heat transfer coefficient of nanofluids were 4.63, 11.47, and 20.20% for nanoparticle loadings of 0.24, 0.60, and 1.18 vol.%, respectively. On the other hand, for turbulent flow, the corresponding heat transfer increases were 4.04, 10.33, and 21.87%.
A numerical study was performed to investigate the thermal performance characteristics of an enhanced tube heat exchanger fitted with punched delta-winglet vortex generators. Computational fluid dynamics modeling was applied using the k–ε renormalized group turbulence model. Benchmarking was performed using the results of the experimental study for a similar geometry. Attack angles of 30°, 50°, and 70° were used to investigate the heat transfer and pressure drop characteristics of the enhanced tube. Flow conditions were considered in the turbulent region in the Reynolds number range of 9100 to 17,400. A smooth tube was employed for evaluating the increment in the Nusselt number and the friction factor characteristics of the enhanced tube. The results show that the Nusselt number, friction factor, and thermal performance factor have a similar tendency. The presence of this insert offers a higher thermal performance factor as compared to that obtained with a plain tube. Vortex development in the flow structure aids in generating a vortex flow, which increases convective heat transfer. In addition, as the angle is varied, it is observed that the largest attack angle provides the highest thermal performance factor. The greatest increase in the Nusselt number and friction factor, respectively, was found to be approximately 3.7 and 10 times greater than those of a smooth tube. Through numerical simulations with the present simulation condition, it is revealed that the thermal performance factor approaches the value of 1.1. Moreover, the numerical and experimental values agree well although they tend to be different at high Reynolds number conditions. The numerical and experimental values both show similar trends in the Nusselt number, friction factor, and thermal performance factor.
This research work reports on the potential of bagasse, a solid waste from sugar factories, to produce activated-carbon (AC) as an adsorbent. The activation was conducted under 500, 600, and 700 °C using steam as the activation agent to produce AC500, AC600, and AC700, respectively. The prepared-materials were characterized to understand their elemental content, surface morphology, thermal properties, functional groups identification, surface area, and pore size. AC700 provided the highest surface area of 592.36 m2/g and indicated the contribution of mesopores distributes along 1.5–8.0 nm of pore size. Therefore, an adsorption test was conducted with AC700 as adsorbent. The results show that methylene blue (MB) adsorption reached equilibrium after 30 min of adsorption time. The adsorption isotherm applied to a monolayer Langmuir isotherm was fitted by linearization, resulting in a constant R2 of 0.999. The MB adsorption to AC700 favorably occurred, as proven by the Freundlich parameter 1/n of 0.881, which is less than 1. The Dubinin-Radushkevich isotherm confirmed that the adsorption proceeded through physical interaction with adsorption energy of 3.536 kJ/mol.