Ammonia is considered to be a potential medium for hydrogen storage, facilitating CO₂-free energy systems in the future. Its high volumetric hydrogen density, low storage pressure and stability for long-term storage are among the beneficial characteristics of ammonia for hydrogen storage. Furthermore, ammonia is also considered safe due to its high auto ignition temperature, low condensation pressure and lower gas density than air. Ammonia can be produced from many different types of primary energy sources, including renewables, fossil fuels and surplus energy (especially surplus electricity from the grid). In the utilization site, the energy from ammonia can be harvested directly as fuel or initially decomposed to hydrogen for many options of hydrogen utilization. This review describes several potential technologies, in current conditions and in the future, for ammonia production, storage and utilization. Ammonia production includes the currently adopted Haber–Bosch, electrochemical and thermochemical cycle processes. Furthermore, in this study, the utilization of ammonia is focused mainly on the possible direct utilization of ammonia due to its higher total energy efficiency, covering the internal combustion engine, combustion for gas turbines and the direct ammonia fuel cell. Ammonia decomposition is also described, in order to give a glance at its progress and problems. Finally, challenges and recommendations are also given toward the further development of the utilization of ammonia for hydrogen storage.

Decarbonization plays an important role in future energy systems for reducing greenhouse gas emissions and establishing a zero-carbon society. Hydrogen is believed to be a promising secondary energy source (energy carrier) that can be converted, stored, and utilized efficiently, leading to a broad range of possibilities for future applications. Moreover, hydrogen and electricity are mutually converted, creating high energy security and broad economic opportunities toward high energy resilience. Hydrogen can be stored in various forms, including compressed gas, liquid hydrogen, hydrides, adsorbed hydrogen, and reformed fuels. Among these, liquid hydrogen has advantages, including high gravimetric and volumetric hydrogen densities and hydrogen purity. However, liquid hydrogen is garnering increasing attention owing to the demand for long storage periods, long transportation distances, and economic performance. This paper reviews the characteristics of liquid hydrogen, liquefaction technology, storage and transportation methods, and safety standards to handle liquid hydrogen. The main challenges in utilizing liquid hydrogen are its extremely low temperature and ortho- to para-hydrogen conversion. These two characteristics have led to the urgent development of hydrogen liquefaction, storage, and transportation. In addition, safety standards for handling liquid hydrogen must be updated regularly, especially to facilitate massive and large-scale hydrogen liquefaction, storage, and transportation.

With every passing second, we witness the effect of the global environmental impact of fossil fuels and carbon emissions, to which nations across the globe respond by coming up with ambitious goals to become carbon-free and energy-efficient. At the same time, electric vehicles (EVs) are developed as a possible solution to reach this ambitious goal of making a cleaner environment and facilitating smarter transportation modes. This excellent idea of shifting towards an entirely EV-based mobility industry and economy results in a range of issues that need to be addressed. The issues range from ramping up the electricity generation for the projected increase in consumption to developing an infrastructure that is large enough to support the higher demand for electricity that arises due to the market penetration of EVs. Vehicle to grid (V2G) is a concept that is largely in a testing phase in the current scenario. However, it appears to offer a solution to the issues created by a mobility sector that the constantly growing EV fleet will dominate. Furthermore, the integration of EVs with the grid seems to offer various cost-wise and environment-wise benefits while assisting the grid by tapping into the idle energy of parked EVs during peak hours. This review aims to present some of the possible ancillary service potentials of such a system while also discussing the potential challenges, impacts, and future market penetration capabilities of V2G technology.