The molecular structure of coal is complex, and the existing research methods are limited, so it is difficult to clarify its influence mechanism on the spontaneous-combustion characteristics of coal. In this paper, the previous extraction, FTIR, TPR, TG-DSC and other experimental results are combined to analyze the extraction weakening effect and the correlation analysis of the spontaneous-combustion characteristic parameters of raffinate coal. The results show that extraction can destroy the connection bond of coal molecules, change the content of dominant active groups in the coal spontaneous-combustion reaction, increase the lower limit of the key temperature nodes of coal spontaneous-combustion or extend the temperature range, resulting in an increase in the ignition-point temperature of coal and a decrease in coal quality. This paper will provide a theoretical basis for the study of the microscopic mechanism of coal spontaneous-combustion and then provide new ideas for the development of an active prevention and control technology for coal spontaneous-combustion.

During narrow coal pillar mining, a high-temperature point can easily form inside the coal pillar, leading to CSC. This study aims to investigate the effect of key layout parameters of a bending heat pipe on the heat transfer from a coal pillar oxidation heat source. The bending heat pipe (Tianjin Xinhua Energy Equipment Technology Co., Ltd., Tianjin, China) heat transfer model was constructed using the Fluent software 2021 R1; meanwhile, the effects of heat transfer of non-uniform and uniform temperature fields under different spacings (30 cm, 40 cm, 50 cm) of a single heat pipe and multiple heat pipes were studied. According to our findings, the maximum temperature error between the simulated and experimental temperature fields in the bent heat pipe under identical operating conditions is 3.8 °C, which verifies the model’s feasibility. The temperature field in each section of the coal pillar exhibits a “wave-like” change trend in the heat pipe, with the heat transfer effect diminishing markedly as the spacing increases. Considering the thermal effect and on-site operation feasibility, the optimal spacing of the two bending heat pipes is determined to be 30–40 cm. These research results can offer a theoretical foundation for the application of bending heat pipes in the advanced prevention of the hidden danger of CSC in narrow coal pillar mining.