The concrete–rock interfacial transition zone (ITZ) is generally considered the weak layer in hydraulic engineering, for it is more permeable than the intact concrete or rocks. The water permeability of the ITZ is a critical parameter concerned with structural safety and durability. However, the permeability and pore structure of the ITZ has not been investigated previously, and the mathematical model of ITZ permeability has not been established. This study performed multi-scale experiments on the concrete–rock ITZ with various rock types (limestone, granite, and sandstone). A series of quantitative and qualitative analysis techniques, including NMR, SEM-EDS, and XRD, characterize the ITZ pore structures. The controlled constant flow method was used to determine the permeability of the concrete, rock, and ITZ. The mathematical model of ITZ permeability was proposed using the fractal theory. The consistency between the experimental data and the proposed model indicates the reliability of this study. The results of the experiment show that ITZ permeability is between 4.08 × 10⁻¹⁸ m² and 5.74 × 10⁻¹⁸ m². The results of the experiment and the proposed model could determine ITZ permeability in hydraulic structure safety and durability analysis.

Carbon dioxide (CO₂) may infiltrate into the caprock and displace brine water in the caprock layer. This causes two effects: one is the caprock swelling induced by the CO₂ adsorption and the other is the caprock dehydration and shrinkage due to CO₂–brine water two-phase flow. The competition of these two effects challenges the caprock sealing efficiency. To study the evolution mechanism of the caprock properties, a numerical model is first proposed to investigate the combined effects of CO₂ adsorption-induced expansion and dehydration-induced shrinkage on the caprock sealing efficiency. In this model, the caprock matrix is fully saturated by brine water in its initial state and the fracture network has only a brine water–CO₂ two-phase flow. With the diffusion of CO₂ from the fractures into the caprock matrix, the CO₂ sorption and matrix dehydration can alter the permeability of the caprock and affect the entry capillary pressure. Second, this numerical model is validated with a breakthrough test. The effects of the two-phase flow on the water saturation, CO₂ adsorption on the swelling strain, and dehydration on the shrinkage strain are studied, respectively. Third, the permeability evolution mechanism in the CO₂–brine water mixed zone is investigated. The effect of dehydration on the penetration depth is also analyzed. It is found that both the shale matrix dehydration and CO₂ sorption-induced swelling can significantly alter the sealing efficiency of the fractured caprock.

The stress sensitivity of shale caprock permeability is a critical factor influencing the long-term security of CO₂ geological sequestration systems. Substantial amounts of clay minerals and nanoscale pore structures reduce shale permeability by trapping water films and throat contraction. Conventional permeability models, which are based on homogeneous pore compressibility, tend to overestimate the contribution of non-effective pores to water mobility, resulting in significant inaccuracies in predicting stress-dependent permeability. Therefore, this study conducted NMR–seepage experiments under varying confining pressures on four shale samples with distinct lithologies to investigate pore compression deformation and permeability stress sensitivity. The T₂ cutoff was subsequently determined through displacement tests to distinguish seepage and adsorption pores. Two distinct constitutive models were calculated with respective compressibility coefficients. Finally, the effects of seepage and adsorption pores on shale permeability stress sensitivity were investigated. The results indicate the following. (1) Increasing confining pressure from 15 to 19 MPa reduces porosity by 14.2–39.6%, with permeability exhibiting a significant decline of 35.6–67.8%. (2) Adsorption pores, stabilized by bound water films of clay minerals, exhibit limited closure under stress. In contrast, seepage pores, influenced by brittle minerals, experience significant deformation, which predominantly contributes to permeability decline. (3) A dual-spring model, differentiating the compressibility of seepage and adsorption pores, reduces prediction errors by 92–96% compared to traditional models. These results highlight that neglecting pore-type-specific compressibility leads to overestimated permeability in heterogeneous shale, with critical implications for optimizing CO₂ storage integrity and hydrocarbon recovery strategies.

《地球科学》(ISSN 1000-2383;CN42-1874/P) (原刊名《地球科学——中国地质大学学报》ISSN 1000-2383;CN42-1233/P)，创刊于1957年，是由教育部主管、中国地质大学主办的综合性地学学术理论期刊，月刊，2015年改名为《地球科学》,她以反映中国地质大学教学与科研最新的、高水平的基础地质、应用地质、资源与环境地质及地学工程技术研究成果为主要任务。

Permeability evolution in remolded fault gouge creates critical uncertainties in geotechnical parameterization for dam foundations. However, the underlying multi-scale mechanisms, including mineral migration and pore structure changes, remain insufficiently understood. This study investigates these mechanisms using remolded plastic-thrust fault gouge from the Yulong Kashi hydropower project in China. We developed an innovative sample preparation method that combines in situ mineral self-cementation and directional compaction. The study integrated multidisciplinary tests including field in situ permeability tests; seepage–stress coupling tests; and micro-scale NMR/XRD/SEM-EDS analyses. Results demonstrate that remolded samples exhibit 1–2 orders of magnitude lower permeability (10⁻⁷ cm/s) than in situ samples (10⁻⁵ cm/s). This significant reduction is primarily caused by the loss of cementing agents and the uniform compaction of remolded samples, which leads to degraded pore connectivity. SEM-EDS analysis highlighted the leaching of cementing materials (such as K⁺, Ca²⁺ ions), while XRD revealed changes in mineral composition, with chlorite dissolution being the primary mineral alteration associated with permeability decay. Additionally, artificially enhanced cohesion distorted the mechanical behavior of the samples. These findings provide an explanation for why conventional laboratory tests tend to underestimate in situ permeability and overestimate shear strength in fault zones. This study establishes microstructure-informed correction frameworks for hydraulic and mechanical parameters in fault-crossing hydraulic engineering applications