Substitution of conventional feedstock with waste based alternatives is one route towards both remediation and reducing costs associated with production of algal biomass. This work explores whether exhaust gases and wastewater can replace conventional feedstock in the production of biomass from Chlorella sorokiniana. Exhaust gases were used to augment production in final effluent, anaerobic digester centrate or in standard medium. Cultures were grown in 1L bottles under illumination of 80 μmol m(-2) s(-1). The results showed an average μmax ranging between 0.04 and 0.07 h(-1), whilst the final biomass yield in different media ranged between 220 and 330 mg L(-1). Lipid yield was increased over time to 31 mg L(-1). CO2 addition resulted in complete nitrogen removal between 48 and 96 h in both final effluent and centrate. The results also indicated that levels of carbon monoxide, carbon dioxide and nitrogen oxides in the exhaust gases can be reduced by between 20% and 95%.

This paper presents experimental studies carried out on a modern direct injection compression ignition engine supplied with a range of straight vegetable oils to investigate the effect of oil fatty acid composition on combustion and emissions. Seven oils, those of corn, groundnut, palm, rapeseed, soybean, sunflower and the micro-algae species Chlorella protothecoides were tested, with all of the fuels heated to 60°C, at constant injection timing and constant ignition timing at a constant engine speed of 1200rpm. All of the vegetable oils exhibited a duration of ignition delay within ±0.6CAD of that displayed by a reference fossil diesel, but displayed much reduced rates of peak heat release rate. The duration of ignition delay was found to increase with an increasing carbon to hydrogen ratio of the vegetable oils, implicating the fatty acid alkyl chain as the primary driver of low temperature reactivity. Peak heat release rates decreased with decreasing vegetable oil viscosity, suggesting a significant degree of fuel cylinder wall and piston bowl impingement. At both injection timings, emissions of NOx were lower for all of the vegetable oils relative to the reference fossil diesel, while those of CO, THC and particulate matter were higher and sensitive to the injection timing

The paper presents an experimental investigation of hydrogen-diesel fuel co-combustion carried out on a naturally aspirated, direct injection diesel engine. The engine was supplied with a range of hydrogen-diesel fuel mixture proportions to study the effect of hydrogen addition (aspirated with the intake air) on combustion and exhaust emissions. The tests were performed at fixed diesel injection periods, with hydrogen added to vary the engine load between 0 and 6 bar IMEP. In addition, a novel in–cylinder gas sampling technique was employed to measure species concentrations in the engine cylinder at two in–cylinder locations and at various instants during the combustion process.The results showed a decrease in the particulates, CO and THC emissions and a slight increase in CO2 emissions with the addition of hydrogen, with fixed diesel fuel injection periods. NOx emissions increased steeply with hydrogen addition but only when the combined diesel and hydrogen co-combustion temperatures exceeded the threshold temperature for NOx formation. The in–cylinder gas sampling results showed higher NOx levels between adjacent spray cones, in comparison to sampling within an individual spray cone

Spent coffee grounds (SCG) are a potentially valuable source of lipids for sustainable production of biofuels. However, there are several feedstock properties and solvent extraction parameters that can impact on the oil yield and quality, potentially reducing the possible environmental benefits of deriving oils from this waste stream. This study presents results of laboratory and pilot plant scale experimental investigations into lipid recovery from spent coffee, determining the effects of solvent extraction variables including duration, SCG-to-solvent ratio and SCG residual moisture. SCG samples from both the industrial production of instant coffee and retail coffee shops were characterized in terms of moisture content, particle size distribution and oil content to identify the impact of these variables on the efficiency of lipid recovery by solvent extraction. The dry weight oil content of the instant SCG samples ranged from 24.2 to 30.4% w/w, while the retail SCG samples contained considerably lower amounts of lipids with their oil content ranging between 13.4 and 14.8% w/w. The highest oil yields were found at an extraction duration of 8 h, while a moisture content of ~2% w/w led to increased yields relative to completely dry samples. A pattern of increasing acidity with decreasing extraction duration was observed, suggesting preferential extraction of free fatty acids (FFA), with the fatty acid (FA) profile of the oil found to be similar to lipids commonly utilized for biofuel production.