Animal manure is considered a valuable organic fertilizer due to its important nutrient content enhancing soil fertility and plant growth in agriculture. Besides its beneficial role as fertilizer, animal manure represents a significant source of volatile organic compounds (VOCs), playing a significant role in atmospheric chemistry. Understanding the composition of VOCs Understanding VOCs from animal manure is crucial for assessing their environmental impact, as they can cause air pollution, odors, and harm to human health and ecosystems. Laboratory studies enhance field measurements by providing a precise inventory of manure emissions, addressing gaps in existing literature. Both approaches complement each other in advancing our understanding of manure emissions. In this context, we conducted an experimental study involving various animal manures (cow, horse, sheep, and goat) taken from a farm in Grignon (near Paris, France). We employed atmospheric simulation chambers within a controlled laboratory environment. The analysis of VOCs involved the combination of Proton Transfer Reaction-Quadrupole ion guide-Time-of-Flight Mass Spectrometry (PTR-QiTOF-MS) and Thermal Desorption-Gas Chromatography-Mass Spectrometry (TD-GC-MS). Using PTR-QiTOF-MS, 368 compounds were detected and quantified within the manure samples. The complementary analysis by TD-GC-MS enhanced our identification of VOCs. Our findings revealed various chemical groups of VOCs, including oxygenated compounds (e.g., ethanol, cresol, acetaldehyde, etc.), nitrogenated compounds (ammonia, trimethylamine, etc.), sulfur compounds (methanethiol, dimethyl sulfide, etc.), aromatic compounds (phenols and indoles), terpenes (isoprene, D-limonene, etc.) and halogenated compounds. Cow manure exhibited the highest VOC emission fluxes, followed by goat, sheep, and horse manures. Notably, oxygenated VOCs were dominant contributors to total VOC emission fluxes in all samples. Statistical analysis highlighted the distinct nature of cow manure emissions, characterized by oxygenated compounds and nitrogenated compounds. In addition, goat manure was isolated from the other samples with high emissions of compounds having both oxygen and nitrogen atoms in their molecular formulas (e.g., CH₃NO₂). The experimental dataset obtained in this study provides an inventory reference for both VOCs and their emission fluxes in animal manures. Furthermore, it highlights odorant compounds and VOCs that serve as atmospheric aerosol precursor. Future studies can explore the effectiveness of various manure treatment methods to promote sustainable agriculture practices.

The growing volume of plastics derived from electronic waste (e-waste) underscores the imperative for environmentally sustainable strategies for the management of this waste. In light of the paramount importance of this issue, a pilot demonstrator for the decontamination of polymers containing Brominated Flame Retardants (BFRs) has been developed. The objective is to investigate the potential for decontaminating BFR-containing polymers from e-waste via UV-visible irradiation using a rotatory laboratory pilot operating under primary vacuum conditions. This report focuses on binary model blends composed of 90 weight% (wt%) poly(Acrylo-Butadiene-Styrene) (ABS) pellets and 10 wt% Deca-Bromo-Diphenyl Ether (DBDE), which is one of the most toxic BFRs. The efficiency of the irradiation process was evaluated as a function of pellet diameter and irradiation time using Fourier Transform InfraRed spectroscopy (FTIR) and High-Resolution Laser Desorption/Ionization Mass Spectroscopy (HR-LDI-MS). As a consequence, ABS + DBDE achieved a decontamination efficiency of 97% when irradiated with pellets of less than 1 mm in diameter for a period of 4 h. Additionally, the thermal behavior of the irradiated samples was investigated through thermogravimetric analysis and differential scanning calorimetry. It was thus established that the application of UV-visible irradiation had no significant impact on the overall thermal properties of ABS.

Kawssar Mujtaba HAIDER1 The paper titled « Environmental Impact of PCDD/F Emissions from MSWI of Sant Adrià de Besòs: A 20-Year Follow—Up Study’s addresses the critical issue of pollutant emissions from municipal solid waste incineration (MSWIs). T...