Polyurethane foams constitute highly problematic waste due to their low density and consequently large volume. Among the most promising recycling approaches, the glycolysis of polyurethane waste stands out and was extensively discussed in this article. Existing literature reviews lack a detailed analysis of glycolysis processes and a clear presentation of the most important data. However, in this review, the scientific literature on glycolysis has been thoroughly examined and updated with the latest research in the field. The article provides an overview of glycolysis methods, categorized into rigid and flexible foams, along with a review of the catalysts and process conditions employed. Additionally, this study offers a comprehensive analysis of industrial methods protected by active patents, which has not been previously explored in the literature. This detailed examination of patent information adds significant value to the review and distinguishes it from others. Furthermore, this review also aims to introduce the main types of polyurethanes and their properties. It outlines the fundamentals of recycling strategies, thermomodernization trends, and environmental considerations, highlighting the critical role of recycling in the industry. The article serves as a complete foundation for exploring new alternative methods in this field.

This study investigates the feasibility of incorporating chemically recycled polyol (glycolysate), derived from semi-rigid polyurethane waste from the building industry, into rigid PUF formulations intended for thermal insulation applications. Glycolysis was performed using a diethylene glycol–glycerol mixture (4:1) at 185 °C in the presence of a dibutyltin dilaurate (DBTDL) catalyst. The resulting glycolysate was characterized by a hydroxyl number of 590 mg KOH/g. Foams containing 5–50% recycled polyol were prepared and described in terms of foaming kinetics, cellular structure, thermal conductivity, apparent density, mechanical performance, dimensional stability, flammability, and volatile organic compound (VOC) emissions. The incorporation of glycolysate accelerated the foaming process, with the gel time reduced from 44 s to 16 s in the sample containing 40% recycled polyol, enabling a reduction in catalyst content. The substitution of up to 40% virgin polyol with recycled polyol maintained a high closed-cell content (up to 87.7%), low thermal conductivity (λ₁₀ = 26.3 mW/(m·K)), and dimensional stability below 1%. Additionally, compressive strength improvements of up to 30% were observed compared to the reference foam (294 kPa versus 208 kPa for the reference sample). Flammability testing confirmed compliance with the B2 classification (DIN 4102), while preliminary qualitative VOC screening indicated no formation of additional harmful volatile compounds in glycolysate-containing samples compared to the reference. The results demonstrate that glycolysate can be effectively utilized in high-performance insulation materials, contributing to improved resource efficiency and a reduced carbon footprint.