The wastewater problem is becoming an increasingly significant environmental issue affecting various aspects of human activities. The generation of reactive oxygen species (ROS) in water through certain physicochemical processes, which can oxidise or degrade various organic and chemical compounds, offers an effective purification method. The main advantage of these methods is the elimination of chemical reagents. The aim of this work is to investigate the possibility of regulating the ROS content in water by altering the characteristics of the plasma discharge that occurs under hydrodynamic cavitation in the water flow. The ROS concentration was determined using the permanganate oxidation titration technique. It was found that the content of various reactive oxygen species in water after treatment can be controlled by varying the power of the electrical pulses applied. Additionally, this study obtained the dependence of the ROS concentration in treated water samples on storage time, with results indicating that sonoplasma treatment has a prolonged effect on the antibacterial properties of water. The analysis of water samples using a biological test culture of Salmonella typhimurium revealed the bacteriostatic properties of the water for at least 48 h after sonoplasma discharge treatment.
Textiles and nonwovens (including those used in ventilation systems as filters) are currently one of the main sources of patient cross-infection. Healthcare-associated infections (HAIs) affect 5–10% of patients and stand as the tenth leading cause of death. Therefore, the development of new methods for creating functional nanostructured coatings with antibacterial and antiviral properties on the surfaces of textiles and nonwoven materials is crucial for modern medicine. Antimicrobial filter technology must be high-speed, low-energy and safe if its commercialization and mass adoption are to be successful. Cerium oxide nanoparticles can act as active components in these coatings due to their high antibacterial activity and low toxicity. This paper focuses on the elaboration of a high-throughput and resource-saving method for the deposition of cerium oxide nanoparticles onto nonwoven fibrous material for use in air-conditioning filters. The proposed spraying technique is based on the use of an aerodynamic emitter and simultaneous suction. Cerium oxide nanoparticles have successfully been deposited onto the filter materials used in air conditioning systems; the antibacterial activity of the ceria-modified filters exceeded 4.0.
In petroleum production processes, the water used to maintain formation pressure often plays a key role and is pumped into injection wells to compensate for the pressure drop in the formation after oil extraction and displacement of the remaining petroleum products to the development well. The source of such water may be produced by waters extracted together with oil and previously purified from mechanical impurities and hydrocarbons. However, a significant disadvantage of using such water is the presence of pollutants such as sulphur-reducing bacteria (SRB) and a high content of hydrogen sulfide. Traditional purification methods against them show low efficiency. Hydrogen sulfide and SRB are not only a threat of environmental pollution, but they also pose a high risk to pipelines in the petroleum industry due to an increase in the rate of metal corrosion. In this paper, formation water was treated with a field deployment flow-mode plasma discharge unit. A significant decrease in the growth rate of SRB in treated water was achieved. Bacterial growth was suppressed for up to 14 days after three treatment cycles of treatment. The hydrogen sulfide content was reduced by 33% after one cycle of plasma discharge water treatment.
The wastewater problem is becoming an increasingly significant environmental issue affecting various aspects of human activities. The generation of reactive oxygen species (ROS) in water through certain physicochemical processes, which can oxidize or degrade various organic and chemical compounds, offers an effective purification method. The main advantage of these methods is the elimination of chemical reagents. Aim of this work is to investigate the possibility of regulating the ROS content in water by altering the characteristics of the plasma discharge that occurs under hydrodynamic cavitation in the water flow. ROS concentration was determined using the permanganate oxidation titration technique. It was found that the content of various reactive oxygen species in water after treatment can be controlled by varying the power of the electrical pulses applied. Additionally, the study obtained the dependence of ROS concentration in treated water samples on storage time, indicating a prolonged effect of sonoplasma treatment on the antibacterial properties of water. Analysis of water samples using a biological test culture of Salmonella typhimurium revealed bacteriostatic properties of the water for at least 48 hours after sonoplasma discharge treatment.
22 November 2024 in The Journal of Physical Chemistry Letters
Pharmaceutical residues, especially non‐steroidal anti‐inflammatory drugs (NSAIDs), are emerging contaminants that hinder sustainable water management and limit wastewater upcycling. In this work, we address the challenge of wastewater upcycling via the scale‐up of a hybrid advanced oxidation process (AOP) that couples hydrodynamic cavitation (HC) and non‐thermal electrical discharge (ED) plasma, and that will enable the in situ generation of ROS. In order to demonstrate process scalability, the hybrid HC/ED plasma system was initially validated at pilot scale (600 L h −1 ) and subsequently up‐scaled to a semi‐industrial reactor (3200 L h −1 ), specifically designed starting from the pilot unit. The effective exploitation of HC/ED plasma synergy led to the process achieving the quantitative degradation of model pollutants, specifically ibuprofen and diclofenac (10 mg/L), in competitive times (13 passes) and without detectable byproducts, thereby validating the process’ robustness and successful scale‐up. Although current wastewater treatment plants (WWTPs) recover nutrients from sludge, biologically treated effluents still contain pharmaceutical residues. This work therefore, potentially solves this issue by providing a sustainable strategy for complete wastewater upcycling in WWTPs, delivering safe regenerated water for agricultural and irrigation reuse, while closing the water cycle.