Porous-activated carbons (ACs) derived from Moroccan pine cones (PC) were synthesised by a two step-chemical activation/carbonisation method using phosphoric acid (PC-H) and zinc chloride (PC-Z) as activating agents and used for the adsorption of bisphenol A (BPA) from water. Several techniques (TGA/DTA, FT-IR, XRD, SEM and BET) were used to determine the surface area and pore characterisation and variations during the preparation of the adsorbents. The modification significantly increased the surface area of both ACs, resulting in values of 1369.03 m² g⁻¹ and 1018.86 m² g⁻¹ for PC-H and PC-Z, respectively. Subsequent adsorption tests were carried out, varying parameters including adsorbent dosage, pH, initial BPA concentration, and contact time. Therefore, the highest adsorption capacity was observed when the BPA molecules were in their neutral form. High pH values were found to be unfavourable for the removal of bisphenol A from water. The results showed that BPA adsorption kinetics and isotherms followed pseudo-second-order and Langmuir models. Thermodynamic studies indicated that the adsorption was spontaneous and endothermic. Besides, the regeneration of spent adsorbents demonstrated their reusability. The adsorption mechanisms can be attributed to physical adsorption, hydrogen bonds, electrostatic forces, hydrophobic interactions, and π-π intermolecular forces.

Constructed wetlands offer sustainable, decentralized solution for wastewater treatment and reuse in Morocco. This study evaluates and compares four advanced vertical flow constructed wetlands (AVFCWs) incorporating locally sourced reactive media, to evaluate phosphate mining residues as a novel substrate. AVFCWs were designed with different substrate combinations, of pozzolan, phosphate mining residues (CW-B), clay (CW-C), and biochar (CW-D), alongside a control system (CW-A). The systems were operated under hydraulic retention times (HRTs) of 24, 48, and 72 hours corresponding to phase I, II and III respectively. Key water quality parameters in domestic wastewater were monitored, and evapotranspiration driven water losses were quantified. The results revealed that the use of reactive media significantly improved treatment efficiency, with CW-D achieving high removal efficiencies across most parameters. COD and TSS removal reached 80% and 88% respectively at 48h HRT, while nitrogen removal exceeded 82% in optimal configurations. CW-B achieved 76% phosphorus removal at 24h HRT, reaching 88% for CW-C at 72h. All AVFCWs exceeded 85% removal for heavy metals (Cu and Cd), with phosphate residues facilitating metal removal. On the other hand, faecal coliforms reached 3 Log reduction at an HRT of 24 h and decreased in subsequent phases, nevertheless exceeding Moroccan reuse limits. Extending hydraulic retention time improved the AVFCWs performance, but increased water loss (up to 28% at 72h) due to pronounced evapotranspiration in semi-arid to arid regions. Although all substrates demonstrated high performance, phosphate mining residues emerge as promising substrate pending further optimization, supporting circular economy objectives.

Constructed wetlands offer a sustainable, decentralized solution for wastewater treatment and reuse in Morocco. This study evaluated mesocosm-scale advanced vertical flow constructed wetlands (AVFCWs) incorporating locally sourced reactive media to assess phosphate mining residues as a novel substrate. Accordingly, four configurations were compared: a sand-based control (CW-A) and three amended systems combining pozzolan with phosphate mining residues (CW-B), clay (CW-C), and biochar (CW-D), operated in batch mode under hydraulic retention times (HRTs) of 24, 48, and 72 h. The incorporation of reactive media significantly improved treatment efficiency, with CW-D achieving high removal efficiencies across most parameters. COD and TSS removal reached 80% and 88%, respectively, while nitrogen removal exceeded 82% in optimal configurations. Phosphorus removal reached 76% in CW-B and 88% in CW-C. The removal of Cd and Cu exceeded 85% in all systems, with phosphate mining residues demonstrating strong potential for metal immobilization. However, despite these high removal efficiencies, the treated effluent did not meet Moroccan reuse standards for cadmium and fecal coliforms, indicating that single-stage AVFCWs are insufficient for safe agricultural reuse and require additional polishing steps. Extended HRT improved AVFCWs’ performance, but increased water loss, reaching up to 28% due to evapotranspiration. Hence, phosphate mining residues emerge as a promising substrate, pending further optimization, while supporting circular economy objectives.