The increasing requirement and use of dental implant treatments has rendered dental implantology indispensable in dentistry. The aim of this study is to determine the optimum concentration of calcium silicate to be incorporated into a polyetherketoneketone (PEKK) matrix used as an implant material to enhance the bioactivity and mechanical properties of the composite compared with unmodified PEKK. In this study, different weight percentage (wt%) of micro-calcium silicate (m-CS) is incorporated into PEKK with ethanol as a binder. Subsequently, the mixture is dried in a forced convection oven at 120°C and poured into customized molds to fabricate a bioactive composite via compression molding (310°C, 15 MPa, and 20 min holding time) ( n = 5). The mechanical properties and in vitro apatite-forming ability of the composites are investigated. Although an apatite layer is formed on all composites after immersion in simulated body fluid for 7 days, the flexural strength and elastic modulus of the composite increased after the filler load is increased to 15 wt%, whereas it decreased in groups with filler loadings exceeding 15 wt%. The results of this study indicate that the incorporation of 15 wt% m-CS into the PEKK polymeric matrix can improve the bioactivity and mechanical properties of this bioactive composite.
8 February 2022 in International Journal of Biomaterials
During prosthodontic clinical practice, the most commonly reported type of failure is the debonding of teeth to the denture base. Incompatible surface conditions at the tooth/denture base interface result in a lack of bonding. This study aimed to study the influence of different surface modifications of acrylic teeth and thermocycling on shear bond strength to polycarbonate denture base material. Eighty cylinder-shaped samples were fabricated. The tested samples were divided into 4 groups (n = 20). Group A represents the control group, group B represents the mechanical modification of the tooth, while group C and group D represent the chemical treatment of the tooth with ethyl acetate and bonding agent, respectively. Each group was further subdivided into 2 categories depending on the thermocycling procedure (N = 10). All samples were tested for shear bond strength tests. A computer-controlled universal testing machine performed the shear bond test at a 0.5 mm/min crosshead speed. Three-way ANOVA ( ) was used for the statistical analysis of the data. Results show that shear bond strength was significantly affected by the surface treatment, whether it is mechanical or chemical ( ) (B > D > C) compared with a control group (A). However, thermocycling has a nonsignificant decrease in the bond strength values in all experimental groups ( ) (B > D > C > A). The mechanical treatment by creating retentive holes (B) provides better results than the chemical surface treatment with a bonding agent and ethyl acetate (D and C, respectively). This study concluded that various surface conditioning methods affect the bonding strength of acrylic teeth and polycarbonate denture base material with no effect of thermocycling.
4 September 2021 in Nano Biomedicine and Engineering