Overheating and overcharging are the core triggering conditions for the thermal runaway of lithium-ion batteries. Studying the behavioral differences of thermal runaway of lithium-ion batteries under these two conditions is crucial for the safety design and protection of lithium-ion batteries. In this study, we investigated the temperature, pressure, gas generation, and heat generation characteristics of lithium batteries under these two conditions. Under overheating conditions, the release of lattice oxygen in the cathode and the decomposition of the electrolyte trigger a self-catalytic reaction, generating CO₂ (54.7%) and H₂ (29.7%), with a total heat release of 17.6 kJ and a heat accumulation rate of 24.3 W, forming a local high-temperature core area. Under overcharging conditions, the voltage drop, capacity attenuation of 21.1% (2230→1762 mAh), and internal resistance surge (6→21 mΩ) reflect severe damage to the electrode. Accompanied by the oxygenation of the EC electrolyte (CO₃²⁻ + C₂H₄↑), the gas production rate is faster. The middle pressure was 0.601 MPa, and the proportion of CO₂ was 67.4%. However, the triggering of thermal runaway relies on the synergistic effect of internal electrochemical reactions and ohmic heat accumulation, resulting in a relatively low rate of energy accumulation.

Electronic equipment brings great convenience to daily life but also causes a lot of electromagnetic radiation pollution. Therefore, there is an urgent demand for electromagnetic wave-absorbing materials with a low thickness, wide bandwidth, and strong absorption. This work obtained a high-performance electromagnetic wave absorption system by adding conductive carbon spheres (CSs) to the CH₃NH₃PbI₃ (MAPbI₃) absorber. In this system, MAPbI₃, with strong dipole and relaxation polarization, acts dominant to the wave absorber. The carbon spheres provide a free electron transport channel between MAPbI₃ lattices and constructs interfacial polarization loss in MAPbI₃/CS. By regulating the content of CSs, we speculate that this increased effective absorption bandwidth and reflection loss intensity are attributed to the conductive channel of the carbon sphere and the interfacial polarization. As a result, when the mass ratio of the carbon sphere is 7.7%, the reflection loss intensity of MAPbI₃/CS reaches −54 dB at 12 GHz, the corresponding effective absorption bandwidth is 4 GHz (10.24–14.24 GHz), and the absorber thickness is 2.96 mm. This work proves that enhancing conduction loss and interfacial polarization loss is an effective strategy for regulating the properties of dielectric loss-type absorbing materials. It also indicates that organic-inorganic hybrid perovskites have great potential in the field of electromagnetic wave absorption.

The thermal runaway of lithium-ion batteries is a critical factor influencing their safety. Investigating the thermal runaway characteristics is essential for battery safety design. In this study, the thermal runaway characteristics of 18650 lithium-ion batteries under different SOCs were systematically analyzed by experiment and simulation. It was found that at high SOC (100%), the highly lithium state accelerated lattice oxygen release, promoted the formation of LiNiO and intensified electrolytic liquid oxygenation combustion, while at low SOC (20%), the reduction environment dominated, and the metal Ni and residual graphite were significantly enriched. Gas analysis shows that CO₂ and H₂ account for more than 80%, and their proportion is regulated by SOC. Temperature and pressure monitoring showed that the increase in SOC significantly increased the thermal runaway peak temperature (100% SOC up to 508.4 °C) and pressure (0.531 MPa).The simulation results show that when the battery pack is out of control, the ejection fire and explosion pressure wave are concentrated in the middle and upper region (overpressure up to 0.8 MPa). This study reveals the mechanism by which SOC affects the path of product and gas generation by regulating the oxidation/reduction balance, which lays a theoretical and simulation foundation for the safe design of batteries and the quantitative evaluation of thermal runaway.

Explosions, including those from war weapons, terrorist attacks, etc., can lead to damage and overall collapse of bridges. However, there are no clear guidelines for anti-blast design and protective measures for bridges under blast loading in current bridge design specifications. With advancements in intelligent construction, precast segmental bridge piers have become a major trend in social development. There is a lack of full understanding of the anti-blast performance of precast segmental bridge piers. To study the engineering calculation method for blast load acting on a typical precast segmental reinforced concrete (RC) pier in near-field explosions, an air explosion test of the precast segmental RC pier is firstly carried out, then a fluid–structure coupling numerical model of the precast segmental RC pier is established and the interaction between the explosion shock wave and the precast segmental RC pier is discussed. A numerical simulation of the precast segmental RC pier in a near-field explosion is conducted based on a reliable numerical model, and the distribution of the blast load acting on the precast segmental RC pier in the near-field explosion is analyzed. The results show that the reflected overpressure on the pier and the incident overpressure in the free field are reliable. The simulation results are basically consistent with the experimental results (with a relative error of less than 8%), and the fluid–structure coupling model is reasonable and reliable. The explosion shock wave has effects of reflection and circulation on the precast segmental RC pier. In the near-field explosion, the back and side blast loads acting on the precast segmental RC bridge pier can be ignored in the blast-resistant design. The front blast loads can be simplified and equalized, and a blast-resistant design load coefficient (1, 0.2, 0.03, 0.02, and 0.01) and a calculation formula of maximum equivalent overpressure peak value (applicable scaled distance [0.175 m/kg^1/3, 0.378 m/kg^1/3]) are proposed, which can be used as a reference for the blast-resistant design of precast segmental RC piers.