Pressure-gain combustion (PGC) represents a promising alternative to conventional propulsion systems for interplanetary travel due to its key advantages, including higher thermodynamic efficiency, increased specific impulse, and more compact engine designs. However, to elevate this technology to a sufficient technology readiness level (TRL) for practical application, extensive experimental validation, particularly under vacuum conditions, is essential. This study focuses on the performance of a pulsed-detonation combustor (PDC) under near-vacuum conditions, with two primary objectives: to assess the combustor’s ignition capabilities and to characterize the shock wave behavior at the exit plane. To achieve these objectives, high-frequency pressure sensors are strategically positioned within both the vacuum chamber and the combustor prototype to capture the pressure cycles during operation, providing insights into pressure augmentation over a period of approximately 0.5 s. Additionally, the Schlieren visualization technique is employed to analyze and interpret the flow structures of the exhaust jet. The combination of these experimental methods enables a comprehensive understanding of the ignition dynamics and the development of shock waves, contributing valuable data to advance PGC technology for space-exploration applications.