Heterogeneous catalysts play a dual role in transesterification due to their advantages of being separable and reusable. In recent years, heterogeneous catalysts derived from renewable resources have received more attention. In this paper, the production of biodiesel from Xanthoceras sorbifolia bunge oil via transesterification was studied under the action of an ILe@Cu@MOF catalyst. Fourier-Transform Infrared Spectroscopy (FTIR), Raman Spectroscopy, scanning electron microscopy (SEM), Energy-Dispersive X-ray Spectroscopy (EDS), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), Thermogravimetric (TG) and other characterization methods were used to characterize the microstructure and thermal stability of the catalyst and further study the ILe@Cu@MOF catalyst for the preparation of biodiesel from Xanthoceras sorbifolia bunge oil. The results show that the surface of the ILe@Cu@MOF catalyst is attached with a sheet-like structure of isoleucine (ILe), which mainly contains Cu, O, C and N elements. The specific surface area is 19.687 m²/g, and the average pore size is 31.74 nm, which belongs to mesoporous material. The pyrolysis temperature of ILe@Cu@MOF reached 360 °C, indicating that the grafting of ILe had a protective effect on Cu@MOF and increased the pyrolysis temperature of Cu@MOF. At the same time, the water contact angle increased from 86° to 121°, and the material was hydrophobic. The optimum conditions for the preparation of biodiesel were as follows: the amount of catalyst was 3 wt%, the molar ratio of methanol to oil was 35:1, the reaction temperature was 50 °C, and the reaction time was 4 h. At this time, the biodiesel yield was up to 82.85%. Moreover, after five cycles of ILe@Cu@MOF, the yield still reached 73.4%. GC–MS and MNR studies showed that the quality of biodiesel after catalysis was higher. The prepared catalyst can make biodiesel products more sustainable, environmentally friendly and economical, and can provide future prospects for the energy utilization of renewable resources.

The swift exhaustion of natural oil reserves and worsening environmental issues have prompted the quest for an economical method to produce biofuels. The superiority of heterogeneous catalysis promotes the development of bio-based catalysts. Carbon materials prepared from agricultural and forestry biomass waste have good application prospects in catalysis. In the present study, Xanthoceras sorbifolia shell waste was used as the raw material, Xanthoceras sorbifolia Bunge Carbon (XC) was used as the catalyst carrier, and K₂CO₃ was used as the activator to prepare a heterogeneous catalyst (KXC). The heterogeneous catalyst was characterized by scanning electron microscopy-energy dispersion X-ray spectroscopy (SEM-EDS), Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), X-ray diffraction (XRD), and Brunauer–Emmett–Teller (BET) and X-ray photoelectron spectroscopy (XPS) analysis techniques to evaluate its chemical composition, structure, and physical morphology. EDS and XPS revealed the presence of K metal, which provided an alkaline site for the transesterification reaction to produce biodiesel. The biodiesel yield was observed by gas chromatography−mass spectrometry (GCMS). Under the reaction conditions of a methanol-to-oil molar ratio of 12:1, a reaction time of 90 min, a temperature of 65 °C, and a catalyst loading of 4 wt.% using 25KXC-600-4, the yield of biodiesel can reach 95.13 ± 0.82%. After being repeated five times, the yield was still 58.11 ± 3.80%. The catalyst has no waste generation, and has the characteristics of simple preparation and environmental friendliness, which make it a green heterogeneous catalyst for biodiesel production.

Conventional adhesives for plywood are mostly derived from petroleum-based materials and commonly suffer from formaldehyde emission, posing threats to the environment and human health. In this study, a renewable resource, Xanthoceras sorbifolium Bunge oil, was used as the raw material. A high-performance bio-based adhesive was successfully prepared by synthesizing Xanthoceras sorbifolium Bunge oil dimethacrylate (MXOEA) as a reactive diluent, blending it with acrylated epoxy Xanthoceras sorbifolium Bunge oil (AEXO), and introducing 2-isocyanatoethyl methacrylate (IEM) to enhance crosslinking. The effects of the MXOEA/AEXO ratio and the IEM addition level on the properties of the adhesive and the resulting plywood were systematically investigated. The results showed that when the mass ratio of AEXO to MXOEA was 3:7, and the IEM content was 10%, the adhesive exhibited the best bonding performance: the resulting plywood achieved a modulus of rupture of 68.85 MPa, a modulus of elasticity of 8086 MPa, and dry and wet bonding strengths of 3.21 MPa and 2.32 MPa, respectively. Mechanistic analysis indicated that the introduction of IEM moderately reduced the viscosity of the adhesive system. Meanwhile, the isocyanate groups in IEM reacted with the hydroxyl groups on the wood surface, forming a chemical crosslinking structure at the adhesive-wood interface, which is considered one of the reasons for the improved mechanical properties of the plywood. This study provides a formaldehyde-free, high-performance bio-based adhesive derived from Xanthoceras sorbifolium Bunge oil for the field of wood-based composites.