Currently, several organic dyes found in wastewater cause severe contamination problems for flora, fauna, and people in direct contact with them. This research proposes an alternative for the degradation of polluting dyes using ZnO nanoparticles (NPs) synthesized by an ecological route using leaf and root extracts of Ambrosia ambrosioides as a reducing agent (with a weight/volume ratio = 4%). Scanning Electron Microscopy (SEM) was used to determine the morphology, showing an agglomeration of cluster-shaped NPs. Using Transmission Electron Microscopy (TEM), different sizes of NPs ranging from 5 to 56 nm were observed for both synthesized NPs. The composition and structure of the nanomaterial were analyzed by infrared spectroscopy (FT-IR) and X-ray diffraction (XRD), showing as a result that the NPs have a wurtzite-like crystalline structure with crystallite sizes around 32–37 nm for both samples. Additionally, the bandgap of the NPs was calculated using Ultraviolet Visible Spectroscopy (UV–Vis), determining values of 2.82 and 2.70 eV for the NPs synthesized with leaf and root, respectively. Finally, thermogravimetric analysis demonstrated that the nanoparticles contained an organic part after the green synthesis process, with high thermal stability for both samples. Photocatalytic analysis showed that these nanomaterials can degrade four dyes under UV irradiation, reaching 90% degradation for methylene blue (MB), methyl orange (MO) and Congo red (CR) at 60, 100 and 60 min, respectively, while for methyl red (MR) almost 90% degradation was achieved at 140 min of UV irradiation. These results demonstrate that it is effective to use Ambrosia ambrosioides root and leaf extracts as a reducing agent for the formation of ZnO NPs, also evidencing their favorable application in the photocatalytic degradation of these four organic dyes.

The high demand for nanomaterials in the field of industry and science has forced researchers to develop new synthesis methods that are more efficient, economical, and environmentally friendly. At present, the application of green synthesis has taken a great advantage over conventional synthesis methods because it helps with the control of the characteristics and properties of the resulting nanomaterials. In this research, ZnO nanoparticles (NPs) were synthesized by biosynthesis using dried boldo (Peumus boldus) leaves. The resulting biosynthesized NPs had a high purity, quasi-spherical shape with average sizes ranging from 15 to 30 nm and a band gap of ~2.8–3.1 eV. These NPs were used in the photocatalytic activity of three organic dyes. The results showed degradation of 100% methylene blue (MB) in 180 min, 92% methyl orange (MO) in 180 min, and 100% Rhodamine B (RhB) in 30 min of exposure. These results show that the Peumus boldus leaf extract is effective in the biosynthesis of ZnO NPs with good photocatalytic properties.

The growing global population has resulted in a higher demand for energy, leading researchers to prioritize the development of alternative energy sources and the improvement of current technologies. Nanofluids (NFs) are a promising method for enhancing heat transfer and efficiently utilizing solar thermal energy. This study describes the preparation of four NFs: two mono NFs of SiC and HfC containing nanoparticle concentrations ranging from 0.10–1.0 wt.%. Moreover, two hybrid NFs were synthesized within the same concentration range (0.10–1.0 wt.%) of SiC-HfC nanocomposites in proportions of 60 wt.% SiC-40 wt.% HfC and 40 wt.% SiC-60 wt.% HfC, all dispersed in a mixture of ethylene glycol (EG) and distilled water (50EG-50H₂O). The materials were synthesized by carbothermal reduction, and the NFs were prepared using the two-step method. The NFs showed stable dispersion, with HfC and 40SiC-60HfC systems exhibiting the higher zeta potential (ζ) values. Viscosity remained largely unaffected by particle addition. The thermal diffusivity of the NFs was measured by the thermal lens spectroscopy (TLS) technique using 1:20 diluted samples. The hybrid nanofluid 40SiC-60HfC improved diffusivity by 66.93%, presenting a synergistic effect in its performance, highlighting its potential in clean energy systems.