David Rodrigues

Dr. David Rodrigues


Research Focus & Metrics

Academic Career Length

3Years (2024-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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5 November 2024 in Materials
Verified
Journal Article
Open access
PDF file
RLRichard LAFLOTTE
Richard LAFLOTTE
CCCéline Cau Dit Coumes
Céline Cau Dit Coumes
JHJérémy Haas
Jérémy Haas
DRDavid Rodrigues
David Rodrigues
CCCéline Cannes
Céline Cannes
MRMurielle Rivenet
Murielle Rivenet
Beryllium metal is used as neutron moderator and reflector or multiplier in certain types of fission or fusion reactors. Dismantling of these reactors will produce radioactive beryllium waste, classified as low- or intermediate-level waste, that will need to be stabilised and solidified before being sent to disposal. The cementation process is under consideration because it may offer a good compromise between simplicity of implementation, cost, and quality of the final cemented wasteform. Nevertheless, knowledge of the corrosion behaviour of Be metal in a cement-based matrix is still limited, partly due to the high toxicity of Be that complicates testing. This study thus investigates Be corrosion in cement suspensions using potentiometry, voltammetry, and electrochemical impedance spectroscopy. Among the five different investigated systems (Portland cement blended without or with 40 wt.% silica fume, calcium sulfoaluminate clinker blended without or with 15% anhydrite, and calcium aluminate cement), Portland cement blended with 40% silica fume and calcium sulfoaluminate cement comprising 15% anhydrite are the most effective in mitigating beryllium corrosion. They allow reduction in the corrosion current by factors of 4 and 50, respectively, as compared to Portland cement.