Following the core theme of a circular economy, a novel strategy to upcycle cigarette butt waste into platinum group metal (PGM)-free metal nitrogen carbon (M-N-C) electrocatalysts for oxygen reduction reaction (ORR) is presented. The experimental route was composed of (i) the transformation of the powdered cigarette butts into carbonaceous char via pyrolysis at 450 °C, 600 °C, 750 °C and 900 °C, (ii) the porosity activation with KOH and (iii) the functionalization of the activated chars with iron (II) phthalocyanine (FePc). The electrochemical outcomes obtained by the rotating disk electrode (RRDE) technique revealed that the sample pyrolyzed at 450 °C (i.e., cig_450) outperformed the other counterparts with its highest onset (E_on) and half-wave potentials (E_1/2) and demonstrated nearly tetra-electronic ORR in acidic, neutral and alkaline electrolytes, all resulting from the optimal surface chemistry and textural properties.

Trillion of cigarette butts are annually littered without being recycled. This work aims at valorizing the whole cigarette butts and their components (paper, filter and tobacco) into Fe‐N_x‐C electrocatalysts for oxygen reduction reaction (ORR) in acid and alkaline media. The pristine wastes were pyrolyzed at 450 °C, activated with KOH at 700 °C, blended with iron phthalocyanine (FePc) precursor, and heat‐treated at 600 °C to produce a robust Fe‐N_x‐C material with ORR active units. The effect of the cigarette components on the final electrocatalytic activity was evaluated by thoroughly investigating the surface chemistry with XPS. The electrocatalysts displayed similar results among the different components in both media due to comparable surface chemistry, especially concerning the nitrogen functional groups. The highest performance was obtained in alkaline where the electrocatalysts from whole cigarettes and paper (CIGF_450 and CIGPF_450) showed an E_1/2 of 0.89 V vs RHE, slightly larger than that of Pt/C with 40 wt % of Pt, which encouraged to replace Pt‐based electrocatalysts in alkaline fuel cells.

Cigarette butt littering poses a significant environmental challenge, with billions of butts discarded each year, fouling ecosystems with slow-to-decompose cellulose acetate filters that absorb and release harmful compounds. In response, an innovative, sustainable approach for valorizing ballot bin waste (BBW) by extracting high-quality cellulose acetate from cigarette butts was investigated. This green approach eliminates the need for hazardous acids and toxic solvents, resulting in a yield of 30% (w/w) and a degree of substitution (DS) of 2.0–2.5, which is comparable to pure cellulose acetate. The following four essential processes are involved in this process: filter separation, water washing to remove impurities, ethanol purification, and acetone precipitation of the cellulose acetate. This approach not only mitigates environmental harm, but also supports circular economy goals by transforming waste into valuable resources.