Constructed wetlands (CWs) are extensively used as an economical and environmentally friendly sewage treatment under ecological engineering technology. Knowledge of the oxygen in the rhizosphere is of primary importance in understanding the function and regulation of microbial communities and macrophytes. Numerous studies on radial oxygen loss (ROL) have greatly elucidated the mechanism of contaminant removal in CWs. The main sources of oxygen in CWs are atmospheric reoxygenation, macrophyte transmission, and artificial aeration. However, artificial aeration is very expensive, and atmospheric reoxygenation is limited. Therefore, ROL by macrophytes is an essential and economical approach for oxygen input in CWs. In this review, we attempted to study the role of macrophytes in CWs. We described the mechanism of ROL and summarized the methods for determining ROL. We also investigated the role of ROL in contaminant removal in CWs. This review will provide considerable useful information on the oxygen input of CWs.

Manganese oxides and iron oxides have been widely introduced in constructed wetlands (CWs) for sewage treatment due to their extensiveness in nature and their ability to participate in various reactions, but their effects on greenhouse gas (GHG) emissions remain unclear. Here, a set of vertical subsurface-flow CWs (Control, Fe-VSSCWs, and Mn-VSSCWs) was established to comprehensively evaluate which are the better metal substrate materials for CWs, iron oxides or manganese oxides, through water quality and the global warming potential (GWP) of nitrous oxide (N₂O), methane (CH₄), and carbon dioxide (CO₂). The results revealed that the removal efficiencies of chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) in Mn-VSSCWs were all higher than that in Fe-VSSCWs, and manganese oxides could almost completely suppress the CH₄ production and reduce GWP (from 8.15 CO₂-eq/m²/h to 7.17 mg CO₂-eq/m²/h), however, iron oxides promoted GWP (from 8.15 CO₂-eq/m²/h to 10.84 mg CO₂-eq/m²/h), so manganese oxides are the better CW substrate materials to achieve effective sewage treatment while reducing the greenhouse gas effect.