Juan José Valenzuela Expósito

Mr. Juan José Valenzuela Expósito

orcid

Research Focus & Metrics

Academic Career Length

3Years (2024-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

View All Publications
23 December 2024 in Polymers
Verified
Journal Article
Open access
PDF file
JEJuan José Valenzuela Expósito
Juan José Valenzuela Expósito
ECELENA PICAZO CAMILO
ELENA PICAZO CAMILO
FIFrancisco Antonio Corpas Iglesias
Francisco Antonio Corpas Iglesias
In recent years, the construction industry has faced challenges related to rising material costs, labor shortages and environmental sustainability, resulting in an increased interest in modular construction cores composed of recycled materials, such as XPS, PUR, PLW and GFRP, from waste from the truck body industry. Two resins, PUR and polyester, were used to bond these recycled composites. Physical, chemical and mechanical analyses showed that the panels formed with PUR resin had superior workability due to the higher open time of the resin, 11.3% better thermal conductivity than the commercial PLW panel (SP-PLW) and reduced porosity compared to those using polyester resin. The mechanical performance of the panels improved with higher structural reinforcement content (PLW and GFRP). Compared to a commercial panel (SP-PLW), the SP-RCM1 recycled panel showed 4% higher performance, demonstrating its potential for sustainable building applications. Thermal and microscopic characterizations showed good adhesion of the materials in the best performing formulations related to higher thermal stability. Therefore, this research aims to demonstrate the feasibility of using waste from the car industry in the manufacture of sandwich panels for modular construction to address these issues.

Verified
Journal Article
Open access
PDF file
JEJuan José Valenzuela Expósito
Juan José Valenzuela Expósito
ECELENA PICAZO CAMILO
ELENA PICAZO CAMILO
FIFrancisco Antonio Corpas Iglesias
Francisco Antonio Corpas Iglesias
This study explores the development and optimization of TiO2-based photoactive coatings enhanced with silver (Ag)—to boost photocatalytic performance—for application on glass-fiber-reinforced polyester (GFRP) and epoxy (GFRE) composites. The influence of Ag content on the structural, physicochemical, and functional properties of the coatings was evaluated. The TiO2-Ag coating showed the best performance and was tested under UV-A irradiation and visible light (Vis), with high efficiency in VOC degradation, self-cleaning, and microbial activity. The tests were repeated in multiple runs, showing high reproducibility in the results obtained. In GFRP, pollutant and microorganism removal ratios of more than 90% were observed. In contrast, GFRE showed a lower adhesion and stability of the coating. This result is attributed to incompatibility problems with the epoxy matrix, which significantly limited its functional performance. The results highlight the feasibility of using the TiO2-Ag coating on GFRP substrates, even under visible light. Under real-world conditions for 351 days, the coating on GFRP maintained its stability. This type of material has high potential for application in modular building systems using sandwich panels, as well as in facades and automotive components, where self-cleaning and contaminant-control properties are essential.

13 April 2025 in Materials
Verified
Journal Article
Open access
PDF file
ECELENA PICAZO CAMILO
ELENA PICAZO CAMILO
JEJuan José Valenzuela Expósito
Juan José Valenzuela Expósito
RCRaúl Carrillo-Beltrán
Raúl Carrillo-Beltrán
GTGriselda Elisabeth Perea Toledo
Griselda Elisabeth Perea Toledo
FIFrancisco Antonio Corpas Iglesias
Francisco Antonio Corpas Iglesias
The sustainable development of building materials is based on reusing by-products to reduce environmental impact and promote alternatives to traditional materials. In this study, geopolymers were developed from by-products of the mining, ceramic, and thermal industries: slate stone cutting sludge (SSCS) and chamotte (CH) as aluminosilicate sources, and olive stone bottom ash (OSBA) as an alkaline activator, combined with sodium silicate (Na2SiO3). Eight geopolymer families were prepared with constant amounts of SSCS and CH and varying proportions of OSBA/Na2SiO3 (0.88–1.31). The evaluation phase included physical, chemical, mechanical, and microstructural tests. The results showed that the optimum geopolymer formulation (GP E) contained 25% SSCS, 15% CH, and 19% OSBA with a Na2SiO3/OSBA ratio of 1.0, achieving a compressive strength of 24.12 MPa after 28 days of curing. GP E also showed the lowest porosity (19.54%), minimal water absorption (6.86%), and favorable thermal conductivity (0.688 W/mK). Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) confirmed the formation of dense and homogeneous matrices. These results demonstrate the feasibility of manufacturing geopolymers using SSCS, CH, and OSBA as substitutes for traditional binders, promoting sustainable practices, reusing industrial by-products, and reducing carbon emissions in construction.

19 March 2025 in Journal of Building Engineering
Verified
Journal Article
Open access
ECELENA PICAZO CAMILO
ELENA PICAZO CAMILO
RBRaul Carrillo Beltrán
Raul Carrillo Beltrán
JEJuan José Valenzuela Expósito
Juan José Valenzuela Expósito
GTGriselda Elisabeth Perea Toledo
Griselda Elisabeth Perea Toledo
FIFco Antonio Corpas Iglesias
Fco Antonio Corpas Iglesias

7 July 2025 in Sustainability
Verified
Journal Article
Open access
PDF file
ECELENA PICAZO CAMILO
ELENA PICAZO CAMILO
JEJuan José Valenzuela Expósito
Juan José Valenzuela Expósito
RCRaúl Carrillo-Beltrán
Raúl Carrillo-Beltrán
GTGriselda Elisabeth Perea Toledo
Griselda Elisabeth Perea Toledo
FIFrancisco Antonio Corpas Iglesias
Francisco Antonio Corpas Iglesias
The forming methodology influences the physicochemical, mechanical, and microstructural properties. In this study, which aims to develop a geopolymeric material for potential insulation applications in buildings such as vertical walls, geopolymers were developed using industrial wastes from different industries: slate stone cutting sludge (SSCS) and chamotte (CH) were used as precursors, and olive stone bottom ash (OSBA) and sodium silicate (Na2SiO3) were used as alkaline activators. Two forming methods were evaluated: uniaxial pressing and casting of the material, varying the forming method and the liquid/solid ratio. The results showed that the pressed geopolymers achieved higher bulk densities (up to 2.13 g/cm3) and significantly higher compressive strength (28.04 MPa at 28 days), attributable to a higher compactness and degree of geopolymer reaction. In contrast, the casting geopolymers exhibited surface efflorescence, related to slower curing and higher porosity, which reduced their compressive strength (17.88 MPa). In addition, the pressed geopolymers showed better thermal stability and fire performance. These results demonstrate that the variation of the forming method has a direct influence on the material properties of geopolymers, and that the pressing process allows for a reduction of the alkaline activator content, thus reducing its environmental footprint.

10 July 2025 in Materials
Verified
Journal Article
Open access
PDF file
JEJuan José Valenzuela Expósito
Juan José Valenzuela Expósito
ECELENA PICAZO CAMILO
ELENA PICAZO CAMILO
GTGriselda Elisabeth Perea Toledo
Griselda Elisabeth Perea Toledo
FIFrancisco Antonio Corpas Iglesias
Francisco Antonio Corpas Iglesias
This study presents the development of particleboards made from olive tree pruning (OTP) residues and truck industry by-products (RCM), using PUR resin as a binder. Five formulations with different OTP/RCM ratios were designed and physical, thermal, mechanical, chemical and microstructural properties were evaluated. The results showed that increasing the RCM content improves the dimensional stability, reduces water absorption and swelling and decreases thermal conductivity, reaching 0.061 W/mK. At the mechanical level, MOR, MOE and IB values of 7.11, 630 and 0.134 MPa, respectively, were obtained. A higher OTP content allows a reduction in the density of the particleboard (752.67 kg/m3) due to the granulometry of the material. FTIR and SEM analyses confirmed the good integration of the materials with the resin, highlighting a lower porosity and higher compaction in formulations with a high RCM content. These results demonstrate that the combination of agricultural and industrial by-products is feasible to manufacture a sustainable particleboard with customizable properties, promoting the circular economy and reducing the dependence on virgin raw materials in the construction sector.