The application of energy-saving policies in buildings could lead to a decrease in the air exchange rate in dwellings, which could consequently lead to an increase in indoor radon concentration and, therefore, to an increase in resident exposure to ionizing radiation. The aim of the research presented in this paper is to investigate radiological exposure to residents due to the usage of different granites commonly used in Serbia as a building material. From the total of 10 analysed granite samples, a wide range of radon and thoron exhalation rates were found: from <161 μBq m⁻² s⁻¹ to 5220 ± 200 μBq m⁻² s⁻¹ and from <7 mBq m⁻² s⁻¹ to 5140 ± 320 mBq m⁻² s⁻¹, respectively. Assuming a low air exchange rate of 0.2 h⁻¹, the contribution of the measured granite material to the indoor radon concentration could go up to 150 Bq m⁻³. The estimated annual effective doses due to exposure to radon and thoron exhalation from the granite samples were (0.05–3.79) mSv and (<0.01–1.74) mSv, respectively. The specific activity of radionuclides ranged from 6.6 ± 0.5 Bq kg⁻¹ to 131.8 ± 9.4 Bq kg⁻¹ for ²²⁶Ra, from 0.5 ± 0.1 Bq kg⁻¹ to 120.8 ± 6.5 Bq kg⁻¹ for ²³²Th, and from 0.22 ± 0.01 Bq kg⁻¹ to 1321 ± 86 Bq kg⁻¹ for ⁴⁰K. The obtained external hazard index ranged from 0.03 to 1.48, with three samples above or very close to the accepted safety limit of 1. In particular, dwellings with a low air exchange rate (causing elevated radon) could lead to an elevated risk of radiation exposure.

Radon’s radioactive decay is the main natural source of small air ions near the ground. Its exhalation from soil is affected by meteorological factors, while aerosol pollution reduces air ion concentrations through ion-particle attachment. This study aimed to analyze correlations between radon, ions, and air pollution under varying conditions and to assess potential health impacts. Measurements were taken at two sites: in early autumn at a suburban part of Belgrade with relatively clean air, and in late autumn in central Belgrade under polluted conditions, with low temperatures and high humidity. Parameters measured included radon, small air ions, particle size distribution, PM mass concentration, temperature, humidity, and pressure. Results showed lower radon concentrations in late autumn due to high soil moisture and absence of nocturnal inversions. Radon and air ion concentrations exhibited a strong positive correlation for both polarities under suburban conditions, whereas measurements in the urban setting revealed a weak negative correlation, despite radon concentrations in soil gas being approximately equal at both sites. Small ion levels were also reduced, mainly due to suppressed radon exhalation and increased aerosol concentrations, especially ultrafine particles. A strong negative correlation (r < −0.5) was found between small air ion concentrations and particle number concentrations in the 20–300 nm range, while larger particles (300–1000 nm and >1 µm) showed weak or no correlation due to their lower and more stable concentrations. In contrast, early autumn measurements showed a diurnal cycle of radon, characterized by nighttime maxima and daytime minima, unlike the consistently low values observed in late autumn.