The Mössbauer spectroscopy method was used to study the ligand microstructure of natural arsenopyrite (31 specimens) from the ores of the major gold deposits of the Yenisei Ridge (Eastern Siberia, Russia). Arsenopyrite and native gold are paragenetic minerals in the ore; meanwhile, arsenopyrite is frequently a gold carrier. We detected iron positions with variable distribution of sulfur and arsenic anions at the vertexes of the coordination octahedron {6S}, {5S1As}, {4S2As}, {3S3As}, {2S4As}, {1S5As}, {6As} in the mineral structure. Iron atoms with reduced local symmetry in tetrahedral cavities, as well as iron in the high-spin condition with a high local symmetry of the first coordination sphere, were identified. The configuration {3S3As} typical for the stoichiometric arsenopyrite is the most occupied. The occupation degree of other configurations is not subordinated to the statistic distribution and varies within a wide range. The presence of configurations {6S}, {3S3As}, {6As} and their variable occupation degree indicate that natural arsenopyrites are solid pyrite {6S}, arsenopyrite {3S3As}, and loellingite {6As} solutions, with the thermodynamic preference to the formation of configurations in the arsenopyrite–pyrite–loellingite order. It is assumed that in the variations as part of the coordination octahedron, the iron output to the tetrahedral positions and the presence of high-spin Fe cations depend on the physical and chemical conditions of the mineral formation. It was identified that the increased gold concentrations are typical for arsenopyrites with an elevated content of sulfur or arsenic and correlate with the increase of the occupation degree of configurations {5S1As}, {4S2As}, {1S5As}, reduction of the share of {3S3As}, and the amount of iron in tetrahedral cavities.

We investigated the microstructural and crystallographic features of quartz from complex vein systems associated with the development of thrust and shear deformations in Western Transbaikalia using electron back scatter diffraction (EBSD) and optical microscopy. Vein quartz systems were studied to obtain insights on the mechanisms and localization of strains in quartz, in plastic and semibrittle conditions close to the brittle–ductile transition, and their relationship to the processes of regional deformations. Five types of microstructures of vein quartz were distinguished. We established that the preferred mechanisms of deformation of the studied quartz were dislocation glide and creep at average deformation rates and temperatures of 300–400 °C with subsequent heating and dynamic and static recrystallization. The formation of special boundaries of the Dauphiné twinning type and multiple boundaries with angles of misorientation of 30° and 90° were noted. The distribution of the selected types in the differently oriented veins was analyzed. The presence of three generations of vein quartz was established. Microstructural and crystallographic features of vein quartz aggregates allow us to mark the territory’s multi-stage development (with the formation of syntectonic and post-deformation quartz).

This paper examines the mineral and geochemical features of lake sediments and waters in intermittent Lake Taloe, located in a semiarid climate. Minerals that belong to groups of oxides, sulfides, aluminosilicates, carbonates, sulfates, and halides are identified through the use of precision methods. The resulting mineral species are divided by genetic features into two associations: terrigenous and hydrogenic. The terrigenous association includes water-insoluble minerals, while the hydrogenic association combines typical hydrogenic minerals. The regularities of the accumulation and distribution of minerals along the lake laterally and to a depth of up to one meter are also examined. The order of deposition of hydrogenous association minerals from sulfate-chloride lake waters was established. The obtained results are confirmed and supplemented by physicochemical calculations, which show the equilibrium of lake waters with hydroxides, oxides, aluminosilicates, carbonates, and sulfates. It has been established that the formation of minerals mainly occurs through evaporative concentration in conjunction with bedrock weathering.

The bulletin of Irkutsk State University. Series «Earth Sciences»

This paper studies the results of electron backscatter diffraction analysis of naturally deformed polycrystalline olivine. It also defines the dependence of lattice-preferred orientations of grains on their microstructural position and size. The authors detect the basic mechanisms, consequence and thermal dynamic modes of deformation. They also show that the development of a polycrystalline structure is determined by the following consecutive activation of sliding systems (010)[100] → {0kl}[100] → (100)[010] → {100}[001] → {110}[001], when dislocation sliding and diffusion creep change under the temperature decrease from 1000°C to 650°C.

Water distribution in the structure of vein quartz formed as a result of successive plastic deformations associated with dislocation slip and subsequent recrystallization was estimated using infrared microspectroscopic (μFTIR) mapping. Water contained in quartz demonstrates a broad absorption band in the IR range at 2800–3750 cm⁻¹, which indicates its molecular state and suggests the presence of water bearing water inclusions. In addition to water, the presence of an absorption band located at 2341 cm⁻¹ seems to be due to the presence of carbon dioxide in a molecular state. A necessary step before assessing the distribution of volatile components in the quartz structure was to calibrate the boundaries obtained by calculating the intensity ratios of the peaks at 1118 and 1160 cm⁻¹ in the reflectance spectrum and using electron back scatter diffraction (EBSD). A variety of fluid distributions in different elements of the structure was observed. At medium temperatures and medium strain rates, dislocation mass transfer is effective during dislocation slip. At low strain rates and elevated temperatures, the contribution of diffusion creep gradually increases, which facilitates the interaction of volatile components with migrating boundaries. It was found that in the process of successive rearrangements, migration of fluid components occurs within the main elements of the structure due to the redistribution of dislocations between defects of different scale levels. Redistribution of fluid from fluid inclusions as a result of plastic deformations in the quartz structure is one of the ways of relaxing intracrystalline stresses during strengthening of the structure.