With the wide application of nuclear energy, the problem of radioactive pollution has attracted worldwide attention, and the research on the treatment of radioactive wastewater is imminent. How to treat radioactive wastewater deeply and efficiently has become the most critical issue in the development of nuclear energy technology. The radioactive wastewater produced after using nuclear technology has the characteristics of many kinds, high concentration, and large quantity. Therefore, it is of great significance to study the treatment technology of radioactive wastewater in reprocessing plants. The process flow and waste liquid types of the post-treatment plant are reviewed. The commonly used evaporation concentration, adsorption, precipitation, ion exchange, biotechnology, membrane separation, and photocatalysis are summarized. The basic principles and technological characteristics of them are introduced. The advantages and disadvantages of different single and combined processes are compared, and the development trend of future processing technology is prospected.
Petroleum is a continuous and dynamically stable colloidal system. In the process of oil extraction, transportation, and post-treatment, the stability of the petroleum sol system is easily destroyed, resulting in asphaltenes precipitation that can make pore throat, oil wells, and pipelines blocked, thereby damaging the reservoir and reducing oil recovery. In this paper, removing near-well plugging caused by asphaltene deposition with high-power ultrasound is investigated. Six PZT transducers with different parameters were used to carry out the experimental study. Results show that ultrasonic frequency is one important factor for removing colloidal precipitation plugging in cores, it could not be too high nor too low. The optimum ultrasonic frequency is 25 kHz; Selecting transducers with a higher power is an effective way to improve the removal efficiency. The optimum ultrasonic power is 1000 W. With the increase of ultrasonic treatment time, the recovery rate reaches the maximum and tends to be stable. ultrasonic processing time should be controlled within 120 min. Besides, three methods - ultrasonic treatment alone, chemical injection alone, and ultrasound-chemical method - for removing colloidal precipitation plugging are compared. Results indicate that the ultrasound-assisted chemical method is better than chemical injection alone or ultrasonic treatment alone to remove colloidal sediment in the core. Finally, the mechanism of the ultrasonic deplugging technique is analyzed from three aspects: cavitation effect, the thermal effect, and mechanical vibration.
Compressed CO2 energy storage (CCES) is a promising energy storage option with benefits like easy liquefaction, high density, and environmental compatibility.
Different from the conventional gas reservoir, coalbed methane is developed mainly by water drainage, which leads methane desorption after reservoir pressure drop. Water drainage at a reasonable speed in the early development stage is the key for enhancing later gas performance. Therefore, the investigation radius, which reflects the pressure drop region scale, is studied by deconvolution well-test to find the reasonable water drainage speed in the early period. First, the early production data (well-bottom pressure and water rate) are processed by deconvolution algorithm, and then the pressure data under unit rate is obtained to invert the comprehensive reservoir permeability and investigation radius. This deconvolution method can save the cost of the conventional well-test, and avoid reservoir damage caused by frequent well shut-off. The feasibility of the deconvolution test method is verified by comparing its interpretation results with those of the conventional pressure drop/build-up test. For a field application, the 29 wells’ comprehensive permeability are inverted by the deconvolution well-test using early water production data of Hancheng block. Furthermore, their investigation radius and pressure drawdown gradient are calculated, and the performance optimization is determined by relationship analysis between working fluid level and steady gas production rate. We find that well-bottom pressure and reservoir pressure should decrease steadily in the early development stage, with the working fluid level declining less than 1 m/d (1 m per day) in wellbore, and the pressure drawdown gradient declining less than 2.8 MPa/100 m.
In recent years, the monolithic material has been developed increasingly in the high performance liquid phase field, and it could also be applied in the field of catalyst, as a monolithic catalyst carrier, since it has a large specific surface area, and could be customized based on the mould. The monolithic catalyst is characterized with many advantages such as low bed pressure, high physical efficiency and small amplification effect. The most impotant part refers to the preparation of copper-based catalyst. The impregnation method is used to produce CuO-ZnO monolithic catalyst and CuO-ZnO-ZrO2 monolithic catalyst with the prepared monolithic silica-alumina carrier. The fixed bed microreactor is used to investigate the effect of copper-based catalyst on the process in which carbon dioxide is used to produce methanol through hydrogenation. The metal salt is added into the sol-gel process, which could form the M-O-Si bond, thus make the metal-containing catalytic material obtain good mechanical strength, and make it possible to be introduced into the acidic center generally. The metal-containing catalytic material carrier also has macropores and mesopores. The presence of large pores could make the molecular mass transfer more effective, while the presence of mesopores could increase the specific surface area of the material. In this paper, the experimental study has been conducted on the production of methanol through hydrogenation of CO2 under different catalysts, to mainly investigate the effect of catalysts with different catalytic performance on the reaction.