Infrared thermography is a growing technology in the engineering geological field both for the remote survey of rock masses and as a laboratory tool for the non-destructive characterization of intact rock. In this latter case, its utility can be found either from a qualitative point of view, highlighting thermal contrasts on the rock surface, or from a quantitative point of view, involving the study of the surface temperature variations. Since the surface temperature of an object is proportional to its emissivity, the knowledge of this last value is crucial for the correct calibration of the instrument and for the achievement of reliable thermal outcomes. Although rock emissivity can be measured according to specific procedures, there is not always the time or possibility to carry out such measurements. Therefore, referring to reliable literature values is useful. In this frame, this paper aims at providing reference emissivity values belonging to 15 rock types among sedimentary, igneous and metamorphic categories, which underwent laboratory emissivity estimation by employing a high-sensitivity thermal camera. The results show that rocks can be defined as “emitters”, with emissivity generally ranging from 0.89 to 0.99. Such variability arises from both their intrinsic properties, such as the presence of pores and the different thermal behavior of minerals, and the surface conditions, such as polishing treatments for ornamental stones. The resulting emissivity values are reported and commented on herein for each different studied lithology, thus providing not only a reference dataset for practical use, but also laying the foundation for further scientific studies, also aimed at widening the rock aspects to investigate through IRT.

Contamination by Light Non-Aqueous Phase Liquids (LNAPL) represents a challenge due to the difficulties encountered in its underground assessment and recovery. The major risks arising from subsoil LNAPL accumulation face human health and environment, gaining a social relevance also in the frame of a continuously changing climate. This paper reports on a literature review about the underground contamination by LNAPL, with the aims of providing a categorization of the aspects involved in this topic, analyzing the current state of the art, underlying potential lacks and future perspectives. The review was focused on papers published in the 2012-2022 time-interval, in journals indexed in Scopus and WoS databases, by querying "LNAPL" within article title, abstract and/or key words. 245 papers were collected and classified according to three "key approaches" -namely laboratory activity, field based-data studies and mathematical simulations- and subordinate "key themes", so to allow summarizing and commenting the main aspects based on the application setting, content and scope. Results show that there is a wide experience on plume dynamics and evolution, detection and monitoring through direct and indirect surveys, oil recovery and natural attenuation processes. Few cues of innovations were found regarding both the use of new materials and/or specific field configuration for remediation, and the application of new techniques for plume detection. Some limitations were found in the common oversimplification of the polluted media in laboratory or mathematical models, where the contamination is set within homogeneous porous environments, and in the low number of studies focused on rock masses, where the discontinuous hydraulic behavior complicates the address and modeling of the issue. This paper represents a reference for a quick update on the addressed topic, along with a starting point to develop new ideas and cues for the advance in one of the greatest environmental banes of the current century.