Unique hybrid nanostructure, which consists of multi-wall carbon nanotube (MWCNT) stems and MoS2 nanosheet (NS) leaves, are prepared by a hydrothermal method. The fabricated material can be potentially used as an electrocatalyst for the hydrogen evolution reaction (HER). To our knowledge, as the reaction medium, water is firstly utilized to the synthesis of the 1T phase MoS2 NSs which uniformly grow on the carbon-based materials. As a result, a nanohybrid catalyst with excellent HER electrocatalytic properties, which included an onset potential of as low as 50 mV, a Tafel slope of 43 mV dec−1, and remarkable cycling stability, is produced. The observed outstanding catalytic performance can be attributed to the uniform distribution of the metallic 1T phase of the MoS2 NSs, which are characterized by the presence of multiple active edges as well as the effective electron transport route provided by the conductive MWCNT substrate. This work demonstrates the high potential of the synthesized HER catalyst and proposes a novel, efficient, environmentally friendly, and inexpensive method for its fabrication.
With the development of low-power technology in electronic devices, the wireless sensor network shows great potential in applications in health tracing and ocean monitoring. These scenarios usually contain abundant low-frequency vibration energy, which can be collected through appropriate energy conversion architecture; thus, the common issue of limited battery life in wireless sensor devices could be solved. Traditional energy-converting structures such as the cantilever-beam type or spring-mass type have the problem of high working frequency. In this work, an eccentric pendulum-based electromagnetic vibration energy harvester is designed, analyzed, and verified with the finite element analysis method. The pendulum that contains alternative distributed magnets in the outer side works as a rotor and has the advantages of a simple structure and low center frequency. The structure size is well scalable, and the optimal output performance can be obtained by optimizing the coil thickness and width for a given diameter of the energy harvester. The simulation results show that the energy harvester could work in ultra-low frequencies of 0.2–3.0 Hz. A full-scale prototype of the energy harvester is manufactured and tested. The center working frequency is 2.0 Hz with an average output power of 8.37 mW, which has potential for application in driving low-power wireless sensor nodes.
25 September 2019 in ACS Applied Materials & Interfaces