Vinasse is acidic, dark brown wastewater obtained as a residue from the alcohol distillation process, the main component of which is water, in addition to mineral nutrients and a high organic load. Electrocoagulation (EC) is a technology that generates coagulating substances in situ by oxidizing sacrificial anodes through an electric current applied to the electrodes. During the last decade, the electrocoagulation process has been intensively investigated in several reviews, due to its ease of operation, versatility, sustainability and low environmental impact. The objective of the present work has been to make a general review of the EC process, its principle, reaction mechanism and operating parameters involved in the electrocoagulation process. In this research, the PRISMA method was used for the analysis of articles from different databases such as Scopus, ScienceDirect and Google Scholar. This review collects numerous studies of the EC process in stillage wastewater treatment and makes a comparison between these experimental results mainly in terms of chemical oxygen demand removal. In addition, this review makes a comprehensive analysis of EC coupled to other processes, taking into account their operating parameters and stillage contaminant removal efficiency. The conclusion of this research points out that electrocoagulation coupled with other treatment processes is very necessary because it reduces energy consumption and increases the rate of pollutant removal from wastewater.

Hydrogen, as a clean energy source, has enormous potential in addressing global climate change and energy security challenges. This paper discusses different hydrogen production methodologies (steam methane reforming and water electrolysis), focusing on the electrolysis process as the most promising method for industrial-scale hydrogen generation. The review delved into three main electrolysis methods, including alkaline water electrolysis, proton exchange membrane electrolysis, and anion exchange membrane electrolysis cells. Also, the production of hydrogen as a by-product by means of membrane cells and mercury cells. The process of reforming natural gas (mainly methane) using steam is currently the predominant technique, comprising approximately 96% of the world’s hydrogen synthesis. However, it is carbon intensive and therefore not sustainable over time. Water, as a renewable resource, carbon-free and rich in hydrogen (11.11%), offers one of the best solutions to replace hydrogen production from fossil fuels by decomposing water. This article highlights the fundamental principles of electrolysis, recent membrane studies, and operating parameters for hydrogen production. The study also shows the amount of pollutant emissions (g of CO₂/g of H₂) associated with a hydrogen color attribute. The integration of water electrolysis with renewable energy sources constitutes an efficient and sustainable strategy in the production of green hydrogen, minimizing environmental impact and optimizing the use of clean energy resources.

Atmospheric pollution results from toxic gases in low concentrations, originating from natural processes and human activities. These gases interact with each other in the presence of solar radiation, forming much more complex compounds that contribute to the formation of photochemical smog. This study presents a mathematical model to estimate the daily concentrations of primary and secondary pollutants, assuming that spatial variation is not considered within a control volume. The model includes nitrogen oxides, ozone, hydrocarbons, aldehydes, alcohols, and other gases, which are related through 52 chemical and photochemical reactions with rate constants that depend on factors such as the time of day and temperature. The model formulation results in 31 ordinary differential equations that are solved using a variable-step algorithm in MATLAB R2019a. Two scenarios are simulated: the “closed-box” model (CBM), where there are no inflows or outflows of gaseous flux, and the “open-box” model (OBM), which includes inflows and outflows within the control volume. The OBM is particularly useful for predicting concentrations during thermal inversion episodes. The results show that several pollutants reach their maximum concentrations at midday, suggesting an increase in the formation of secondary pollutants under high solar radiation, especially in the closed-box model. In the open-box model, concentration peaks shift toward the afternoon. To compare both models, the closed-box system conditions are considered, incorporating airflow into the open-box model without accounting for pollutants transported by this flow. The complex nonlinear dynamics observed in the pollutants highlight the combined influence of solar radiation, temperature, and emission rates on air quality. This study underscores the usefulness of mathematical models in developing effective mitigation strategies and assessing environmental and public health impacts.

Given the problems related to drinking water supplies in rural and economically disadvantaged regions, point-of-use disinfection technologies are a viable alternative to improve access to drinking. Electrochlorinators are devices that produce chlorine-based disinfectants onsite via the electrolysis of a sodium chloride solution. In this research, we have constructed an innovative laboratory-scale three-compartment cell that includes two ion exchange membranes, fixed between two electrodes; in the anodic compartment, an acidic mixture of chlorine-based species (Cl₂, HClO, HCl and ClO⁻) is obtained, and, in the cathodic compartment, an alkaline solution is present (NaOH and hydrogen gas), while the central compartment is fed with a sodium chloride solution. The Taguchi methodology was used to examine the impact of the process operating conditions on the results obtained. The effects of the electrical potential levels (4.5, 6 and 7 V), electrolysis times (30, 60 and 90 min) and initial sodium chloride concentrations (5, 15 and 30 g/L) on the physical and chemical characteristics (concentrations of available chlorine and sodium hydroxide and pH of the solutions) and energy consumption were investigated. Variations in the electrical potential significantly influenced the concentration levels of active chlorine and sodium hydroxide produced, as well as the pH values of the respective solutions. The most favorable conditions for the production of electrolyzed water were an electrical potential of 7 volts, an electrolysis time of 90 min and a concentration of 30 g/L of sodium chloride, which was verified by ANOVA. The maximum concentration of active chlorine reached 290 mg/L and that of sodium hydroxide reached 1450 mg/L without the presence of hypochlorite ions under the best synthesis conditions. The energy consumption was 18.6 kWh/kg Cl₂ and 4.4 kWh/kg NaOH, while the average electric current efficiency for sodium hydroxide formation reached 88.9%. Similarly, the maximum conversion of chloride ions reached 24.37% under the best operating conditions.

Academic engagement and perceived employability are increasingly relevant to how higher education prepares students for changing labor markets, yet their empirical relationship remains theoretically and methodologically fragmented. This systematic review synthesized primary studies that substantively examined both constructs among higher education students. Reporting followed PRISMA 2020. The original Scopus and Web of Science searches were expanded during peer review to ERIC, APA PsycINFO, Education Source, and ProQuest, and one-generation backward and forward citation searching was completed. Across all sources, 627 raw records were consolidated, 119 duplicates were removed, 508 unique records were screened, 17 full texts were assessed, and 14 studies met the eligibility criteria. Evidence was synthesized narratively because study designs, measures, modeled directions, and statistical metrics were not sufficiently comparable for meta-analysis. Twelve studies were cross-sectional and two were longitudinal or time-lagged. The evidence was predominantly consistent with a positive association between engagement and perceived employability, but effect magnitude, dimensional patterns, modeled direction, and explanatory mechanisms varied. Engagement frequently operated as a mediator linking educational, relational, or psychological resources with employability perceptions, whereas several studies modeled perceived employability as an antecedent of engagement. JBI appraisal indicated generally adequate measurement and statistical analysis but recurrent limitations in explicit confounding control and temporal inference. The findings support a cautious, mechanism-oriented interpretation: academic engagement and perceived employability are related, but causal ordering remains unresolved. Future research should prioritize longitudinal, reciprocal, dimension-sensitive, multi-source, and cross-context designs and directly measure sustainable career outcomes rather than treating perceived employability as a proxy for career sustainability.

Generative artificial intelligence (GenAI) is reshaping media and communication, yet research on its semiotic role in meaning-making remains theoretically and methodologically fragmented. This systematic review examines semiotic frameworks, technological modalities, communication contexts, and human–AI agency in research published from 2021 to 26 August 2026. Scopus and Web of Science searches identified 376 records; the final included corpus comprises 128 studies. The synthesis distinguishes between modality-specific concerns: studies of large language models primarily examine interaction and dialogue, whereas text-to-image studies emphasize representation and synthetic imagery. The RAW agency data contained four cases coded as predominantly AI-led, but these classifications changed following a documented text-consistency review, showing that the agency pattern is sensitive to coding decisions. We derive four provisional configurations: instrumental human anchoring, mediated distributed semiosis, co-creative/agentive participation, and contested or unresolved computational semiosis. The studies also reveal interconnected methodological, conceptual, cultural, technological, and governance gaps. These findings suggest that participation in sign production and mediation should be distinguished from claims of autonomous intentional agency; they do not establish whether generative systems possess intentional understanding.