The PCM (phase contrast microscopy) method for asbestos counting needs special sample treatments, hence it is time consuming and rather expensive. As an alternative, we implemented a deep learning procedure on images directly acquired from the untreated airborne samples using standard Mixed Cellulose Ester (MCE) filters. Several samples with a mix of chrysotile and crocidolite with different concentration loads have been prepared. Using a 20x objective lens coupled with a backlight illumination system a number of 140 images were collected from these samples, which along with additional 13 highly fibre loaded artificial images constituted the database. About 7500 fibres were manually recognised and annotated following the National Institute for Occupational Safety and Health (NIOSH) fibre counting Method 7400 as input for the training and validation of the model. The best trained model provides a total precision of 0.84 with F1-Score of 0.77 at a confidence of 0.64. A further post-detection refinement to ignore detected fibres < 5 µm in length improves the final precision. This method can be considered as a reliable and competent alternative to conventional PCM.
12 February 2025 in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Here, we aimed at extending the Near Infrared-Short-wave infrared (NIR-SWIR) spectroscopy approach in characterizing Asbestos Containing Materials (ACM) and Natural Occurring Asbestos (NOA) through the development and testing of a novel portable asbestos mapping tool based on Hyperspectral Imaging (NIR-HSI) tool. This was built using high resolution spectroscopy over a range of about 170 nm around the OH overtone bands (about 1370-1420 nm), a supercontinuum laser for vibrational excitation, compact XYZ translation stages, and dedicated software. The vibrational reflection data measured using this system allowed discriminating different asbestos minerals and to define the methodological basis for their quantification in various matrices. Point scan NIR-SWIR reflectance images with a spatial resolution of about 50 µm allowed successfully mapping asbestos inclusion in proximity of the surface of a set of samples. The experimentation demonstrated the possibility of characterizing asbestos in NOA or ACM directly in situ, through mineral mapping providing qualitative and semi-quantitative information on the asbestos fiber contents.
Asbestos fibers are well-known carcinogens, and their rapid detection is critical for ensuring safety, protecting public health, and promoting environmental sustainability. In this work, short-wave infrared (SWIR) spectroscopy, combined with machine learning (ML), was evaluated as an environmentally friendly analytical approach for simultaneously distinguishing the asbestos type, asbestos-containing materials in various forms, asbestos-contaminated/-uncontaminated soil, and asbestos-contaminated/-uncontaminated cement, simultaneously. This approach offers a noninvasive and efficient alternative to traditional laboratory methods, aligning with sustainable practices by reducing hazardous waste generation and enabling in situ testing. Different chemometrics techniques were applied to discriminate the material classes. In more detail, partial least squares discriminant analysis (PLS-DA), principal component analysis-based discriminant analysis (PCA-DA), principal component analysis-based K-nearest neighbors classification (PCA-KNN), classification and regression trees (CART), and error-correcting output-coding support vector machine (ECOC SVM) classifiers were tested. The tested classifiers showed different performances in discriminating between the analyzed samples. CART and ECOC SVM performed best ( and equal to 1.00), followed by PCA-KNN ( of 0.98–1.00 and equal to 1.00). Poorer performances were obtained by PLS-DA ( of 0.68–0.72 and equal to 0.95) and PCA-DA ( of 0.66–0.70 and equal to 0.95). This research aligns with the United Nations’ Sustainable Development Goals (SDGs), particularly SDG 3 (Good Health and Well-Being), by enhancing human health protection through advanced asbestos detection methods, and SDG 12 (Responsible Consumption and Production), by promoting sustainable, low-waste testing methodologies.
The detection and monitoring of asbestos–cement roofing remain a critical public health and environmental challenge, especially in urban and suburban areas where asbestos-containing materials are still widespread due to their extensive use in the 20th century. Although hyperspectral and high-resolution multispectral remote sensing have proven effective for mapping asbestos–cement roofs, many existing approaches rely on proprietary software, limiting transparency, reproducibility, and large-scale adoption. This study presents a fully reproducible, cost-free Python-based workflow for the detection and temporal monitoring of asbestos–cement roofing using high-resolution multispectral WorldView-3 imagery. The workflow integrates atmospheric correction (using the Py6S radiative transfer model), spatial preprocessing, supervised pixel-based classification, postprocessing, and building-level aggregation within an open framework. A Maximum Likelihood Classifier is applied to VNIR and SWIR data using empirically defined roof typologies to enhance class separability. Pixel-level results are aggregated to the building scale through adaptive thresholding enabling the translation of spectral classifications into meaningful building-level information. Tested over the city of Mantua (Italy), the approach achieved reliable classification performance and enabled multi-temporal comparison to identify changes potentially due to roof remediation. Evaluation metrics (precision, recall, and F1-score) highlight the importance of carefully choosing the building-level threshold. By relying exclusively on open-source tools, the workflow enhances transparency, reproducibility, and scalability for long-term monitoring.