Although there is an important lack of commercial thermoelectric applications mainly due to their low efficiency, there exist some cases in which thermoelectric generators are the best option thanks to their well-known advantages, such as reliability, lack of maintenance and scalability. In this sense, the present paper develops a novel thermoelectric application in order to supply power to volcanic monitoring stations, making them completely autonomous. These stations become indispensable in any volcano since they are able to predict eruptions. Nevertheless, they present energy supply difficulties due to the absence of power grid, the remote access, and the climatology. As a solution, this work has designed a new integral system composed of thermoelectric generators with high efficiency heat exchangers, and its associated electronics, developed thanks to Internet of Things (IoT) technologies. Thus, the heat emitted from volcanic fumaroles is transformed directly into electricity with thermoelectric generators with passive heat exchangers based on phase change, leading to a continuous generation without moving parts that powers different sensors, the information of which is emitted via LoRa. The viability of the solution has been demonstrated both at the laboratory and at a real volcano, Teide (Canary Islands, Spain), where a compact prototype has been installed in an 82 ${}^{°}$C fumarole. The results obtained during more than eight months of operation prove the robustness and durability of the developed generator, which has been in operation without maintenance and under several kinds of meteorological conditions, leading to an average generation of 0.49 W and a continuous emission over more than 14 km.

One of the measures to fight against the current energy situation and reduce the energy consumption at an industrial process is to recover waste heat and transform it into electric power. Thermoelectric generators can be used for that purpose but there is a lack of experimental studies that can bring this technology closer to reality. This work presents the design, optimizations and development of two devices that are experimented and compared under the same working conditions. The hot side heat exchanger of both generators has been designed using a computational fluid dynamics software and for the cold side of the generators two technologies have been analysed: a finned dissipater that uses a fan and free convection biphasic thermosyphon. The results obtained show a maximum net generation of $6.9$$\mathrm{W}$ in the thermoelectric generator with the finned dissipater; and $10.6$$\mathrm{W}$ of power output in the generator with the biphasic thermosyphon. These results remark the importance of a proper design of the heat exchangers, trying to get low thermal resistances at both sides of the thermoelectric modules, as well as, the necessity of considering the auxiliary consumption of the equipment employed.

With global warming and rising energy demands, it is important now than ever to transit to renewable energy systems. Thermoelectric (TE) devices can present a feasible alternative to generate clean energy from waste heat. However, to become attractive for large-scale applications, such devices must be cheap, efficient, and based on ecofriendly materials. In this study, the potential of novel silicide-tetrahedrite modules for energy generation was examined. Computer simulations based on the finite element method (FEM) and implicit finite difference method (IFDM) were performed. The developed computational models were validated against data measured on a customized system working with commercial TE devices. The models were capable of predicting the TEGs’ behavior with low deviations ($\le$10%). IFDM was used to study the power produced by the silicide-tetrahedrite TEGs for different $\Delta T$ between the sinks, whereas FEM was used to study the temperature distributions across the testing system in detail. To complement these results, the influence of the electrical and thermal contact resistances was evaluated. High thermal resistances were found to affect the devices $\Delta T$ up to ~15%, whereas high electrical contact resistances reduced the power output of the silicide-tetrahedrite TEGs by more than ~85%.

El dióxido de carbono se ha convertido en un refrigerante ampliamente utilizado en los últimos años en sistemas de compresión de vapor debido a sus excelentes propiedades termodinámicas y medioambientales. Hoy en día, múltiples estudios se centran en mejorar el coeficiente de operación de estos sistemas para disminuir el consumo de las instalaciones frigoríficas y de esta forma cumplir con las normativas medioambientales. Para sistemas de media-baja potencia que utilizan dióxido de carbono como refrigerante las dos soluciones más estudiadas en los últimos años han sido el subenfriador termoeléctrico y el intercambiador recalentador subenfriador. Los trabajos presentes en la literatura acerca de estas tecnologías no son directamente comparables debido a diferentes condiciones de funcionamiento, instalaciones, potencias frigoríficas o condiciones ambientales. Para ello, este estudio presenta una comparativa experimental entre un subenfriador termoeléctrico y un intercambiador recalentador subenfriador para un sistema de compresión de vapor transcrítico que utiliza dióxido de carbono como refrigerante.