Based on the establishment of the original and improved models of the turbine blade, a thermal-fluid-solid coupling method and a finite element method were employed to analyze the internal and external flow, temperature, and thermal stress of the turbine blade. The uneven temperature field, the thermal stress distribution characteristics of the composite cooling turbine blade under the service conditions, and the effect of the thickness of the thermal barrier coating (TBC) on the temperature and thermal stress distributions were obtained. The results show that the method proposed in this paper can better predict the ablation and thermal stress damage of turbine blades. The thermal stress of the blade is closely related to the temperature gradient and local geometric structure of the blade. The inlet area of the pressure side-platform of the blade, the large curvature region of the pressure tip of the blade, and the rounding between the blade body and the platform on the back of the blade are easily damaged by thermal stress. Cooling structure optimization and thicker TBC thickness can effectively reduce the high temperature and temperature gradient on the surface and inside of the turbine blade, thereby reducing the local high thermal stress.
Hydrogen blended with natural gas is one of the best ways for large-scale hydrogen transportation; however, pipeline steels exploited for transferring natural gas have the risk of hydrogen embrittlement. Therefore, the hydrogen damage mechanism and resistance property of different steel pipelines should be carefully examined to select suitable materials for the task mentioned above. The common X42, X52, X70, and AISI 1020 are taken into account as research objects. Their mechanical properties and hydrogen absorption properties in a hydrogen environment are investigated to explore further factors affecting the hydrogen embrittlement of material. Dynamic slow strain rate tensile test results show that these materials exhibit varying hydrogen embrittlement sensitivity in a hydrogen environment. AISI 1020 has the highest hydrogen embrittlement susceptibility, then X70, and X42 presents the lowest one. Generally, hydrogen embrittlement behaviours are strengthened by increasing the current density. As the current density grows, the fracture mode of pipeline steels transforms from the ductile fracture to the quasi-cleavage fracture and finally turns into the cleavage fracture. The hydrogen embrittlement fracture of the tensile specimen results from the action of the HEDE and HELP in various zones. TDS test results indicates that the content of C and Mn significantly influence on the hydrogen solubility in metal materials.
Hydrogen embrittlement (HE) is a critical issue that affects the reliability of hydrogenation reactors. The hydrogen diffusivity/trap characteristics of 2.25Cr-1Mo-0.25V steel are important parameters mainly used to study the HE mechanism of steel alloys. In this work, the hydrogen diffusivity/trap characteristics of heat-treated (annealed) and untreated 2.25Cr-1Mo-0.25V steel were studied using an electrochemical permeation method. The microstructures of both 2.25Cr-1Mo-0.25V steels were investigated by metallurgical microscopy. The effect of cementite on the hydrogen diffusivity/trap mechanisms was studied using thermodynamics-based and Lennard–Jones potential theories. The results revealed that the cementite located at the grain boundaries and at the interfaces of lath ferrite served as a kind of hydrogen trap (i.e., an irreversible hydrogen trap). In addition, hydrogen was transported from ferrite to cementite via up-hill diffusion, thereby supporting the hypothesis of cementite acting as a hydrogen trap.
9 August 2023 in International Journal of Hydrogen Energy
An investigation into the electrochemical corrosion behavior of X80 pipeline steel under different elastic and plastic tensile stress in a CO2-saturated NaCl solution has been carried out by using open-circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopy, and surface analysis techniques. The results show that the corrosion rate of X80 steel first increases and then slightly decreases with the increase of elastic tensile stress, whereas the corrosion rate sharply increases with the increase of plastic tensile stress. Both elastic and plastic tensile stress can enhance steel corrosion by improving the electrochemical activity of both anodic and cathodic reactions. Moreover, compared with elastic tensile stress, plastic tensile stress has a more significant effect. Furthermore, electrochemical reactions for CO2 corrosion and mechanoelectrochemical effect are used to reasonably explain the corrosion behavior of stressed X80 steel in CO2 environment.