Tidal seashell waste represents an abundant, underutilized marine resource that poses environmental disposal challenges but offers potential as a sustainable bio-filler in epoxy composites. This study investigates its incorporation into bio-based epoxy systems to reduce reliance on non-renewable materials and promote circular economy objectives. Processed seashell powder was blended into epoxy formulations, and response surface methodology was applied to optimize filler loading and resin composition. Comprehensive characterization included tensile strength, impact resistance, hardness, density, and thermal conductivity testing, along with microscopy analysis to evaluate filler dispersion and interfacial bonding. The optimized composites demonstrated improved hardness, density, and thermal stability while maintaining acceptable tensile and impact strength. Microscopy confirmed uniform filler distribution at optimal loadings but revealed agglomeration and void formation at higher contents, which can reduce interfacial bonding efficiency. These findings highlight the feasibility of valorizing marine waste as a reinforcing filler in sustainable composite production, supporting environmental goals and offering a scalable approach for the development of durable, lightweight materials suitable for structural, coating, and industrial applications.
28 August 2025 in Thermal Science and Engineering Progress
The growing demand for sustainable and environmentally friendly materials has highlighted the need for innovative alternatives to traditional plastics and composites. This study explores the development of polyurethane-based biocomposites synthesized using hydrogenated safflower oil (HSO), hydrogen gas, and a nickel catalyst. Safflower oil was hydrogenated via a catalytic hydrogenation mechanism, transforming carbon–carbon double bonds into saturated fatty acids. The process, optimized using response surface methodology (RSM), was conducted at 225 °C, 8 atmospheres, and 6 h, achieving a yield of 67%. Hydrogenation improved the physical and chemical properties of the biocomposites. Biocomposites were synthesized by combining HSO with methylene diphenyl diisocyanate (MDI) as a crosslinker. Optimal performance was observed at 2.5% HSO content, enhancing material properties. However, higher HSO content negatively affected biocomposite density and hardness, and surface morphology analyses revealed that increased HSO content led to irregular pore structures. These findings underscore the balance required in material composition to achieve optimal performance. This study presents a novel approach to producing hydrogenation-modified HSO-based biocomposites, providing an eco-friendly and sustainable alternative for industries such as packaging, construction, and automotive applications. The advancements contribute to reducing environmental impact and enhancing the performance of renewable material technologies.
The aim of this study is to investigate the potential applications of pine cones as plant-based waste material in the construction industry. In order to achieve this target, the pine cone particles (PCP) are mixed with cement to create new lightweight concretes. Furthermore, pine tree resin (PTR), acting as a natural bio-polymer binder, is incorporated into selected samples to ascertain its potential as a binder. The pine cones are cut into particles of 2–4 cm, 0–2 cm, and ground into a powder. A series of critical tests is conducted on the novel produced samples, including thermal conductivity, specific heat, density, compressive strength, water absorption rate, and drying rate. The experiments show that thermal conductivity, specific heat capacity, and thermal expansion coefficient decrease as the weight ratio and size of PCP increase. The presence of PTR increases porosity, further decreasing thermal conductivity, specific heat, and thermal expansion coefficients for the majority of samples. The compressive strength values decrease with the presence of PTR and PCP. Regarding durability, the water absorption ratios remain below the critical 30% threshold, making the material suitable for internal applications or external facades protected by coating/plaster or as external coverings.
In this study, a numerical and experimental analysis of a solar collector with roughness elements in the form of stainless-steel scourers on the absorber surface is presented. According to the location type and number of the stainless steel scourers, the absorber surfaces are referred to as the complex surface (C1), less complex surface (C2), and flat surface (C3). A Computational Fluid Dynamics (CFD) analysis was carried out using ANSYS-CFX-R18.2 commercial software. The results were verified with the experimental study. After the numerical study was confirmation with the experimental study, then the detailed investigation was performed by numerical simulations. The extracted results of the numerical and experimental analysis concerned the air temperature and velocity, and thermal efficiency, which varied with respect to the type of collector. As a result, the C1 type yielded the highest air velocity and air temperature, while the lowest values of air velocity and temperature were recorded for the C3 type, according to both the numerical analysis and experimental tests. This trend was similar for the efficiencies. The efficiency was nearly 80% for collectors with stainless-steel scourers, whilst it was 55% for the flat plate collector. The results showed that the experimental and numerical results agreed well.
Expanded clay (exclay) aggregate and cherry tree resin are used in this study to produce a lightweight construction material. Based on the grain diameter, exclays are classified as d = 2–4 mm and d = 4–6 mm. Cement is added to each group as the binder material. The exclay ratios vary as 10%, 20%, 30%, 40% and 50% of the total volume in the samples. The cherry tree resin is poured into the concrete mixture with a ratio of 1% and 1.5% of cement + exclay mixture in order to form artificial pores in each sample group. The produced samples are subjected to some tests, such as thermal conductivity, water absorption and compressive strength. It is determined that due to the increase in exclay ratios and particle diameter, there is an increase in porosity along with water absorption, but there is a decrease in density, thermal conductivity and compressive strength. Hence, these newly produced concretes are recommended for panel walls, brick, concrete briquettes, inner and outer plaster and concrete partition elements.