The grain boundary diffusion process employing a mixed diffusion source, comprising heavy rare-earth elements and low-melting metals, significantly enhances the coercivity (H_cj) of sintered Nd-Fe-B magnets. In the present study, Tb and Ga were deposited onto the surface of Nd-Fe-B magnets to serve as a diffusion source for improving hard magnetic properties. The effects of varying deposition sequences of Tb and Ga on the magnetic properties and microstructure of the magnets were analyzed. The findings demonstrate that TbF₃ grain boundary diffusion facilitated by Ga effectively increases the efficiency of Tb substitution, leading to enhanced coercivity. When Tb and Ga are deposited simultaneously, coercivity shows a notable improvement of 53.15% compared to the untreated magnet, with no reduction in remanence. Additionally, thermal stability is enhanced, resulting in superior overall magnetic properties. Microstructural analysis reveals that Ga promotes the diffusion of Tb into the magnet. In the magnet where Tb and Ga are co-deposited, the formation of a thinner and more uniform (Nd,Tb)₂Fe₁₄B shell–core structure, along with the greater infiltration depth of Tb, leads to a broader distribution of core–shell structures within the magnet. This effectively increases the anisotropy fields (H_A) of the main phase grains, preventing the nucleation of antiferromagnetic domains at the edges of main-phase grains, thereby enhancing coercivity. Furthermore, the corrosion resistance of the magnet subjected to mixed diffusion is improved. This study provides a foundation for producing highly efficient magnets with a lower content of heavy rare-earth elements. The simplicity and flexibility of the process make it highly suitable for industrial applications.

The synthesis of Nd-Fe-B magnetic powders via chemical techniques presents significant promise, but poses challenges due to their inherent chemical instability. In this investigation, Nd-Fe-B hard magnetic particles were synthesized utilizing an eco-friendly and simple microwave-assisted hydrothermal synthetic method. The technique involves the synthesis of the Nd-Fe-B oxide precursor using the microwave-assisted hydrothermal method, followed by reduction–diffusion using CaH₂. The microwave-assisted hydrothermal technique presents a viable approach for preparing Nd-Fe-B precursor particles, offering advantages such as time and energy efficiency and environmental sustainability. The synthesized Nd-Fe-B particles demonstrated a coercivity of up to 2.3 kOe. These magnetic particles hold significant potential for use in high-performance permanent magnets, and can effectively contribute to developing high-energy density exchange-coupled nanocomposite magnets. This study also offers valuable insights into the design and synthesis of additional magnetic materials based on rare earth elements.

This work aims to illustrate the influence of a single electron on the bonding properties and geometric structure of a benzene-like cluster, using B₅O₇ ^+/0/– as an exemplar. The inherent electron deficiency of boron dictates not only the rich structural variety of boron oxide clusters but also their unique electronic characteristics and unconventional bonding schemes. The discovery of cyclic boron oxide clusters has facilitated the study of their unique structures and bonding properties. We report a study of the bonding properties of B₅O₇ ^+/0/– clusters. The B₅O₇ ⁺ clusters exhibit a GM structure consisting of a boroxol core and two terminal OBO groups. The neutral B₅O₇ and anionic B₅O₇ ^– clusters are similar in structure, consisting of a boroxol core and three terminal ligands: a terminal boronyl group and an oxygen group and a terminal OBO group. In contrast to the B₅O₇ ⁺ and B₅O₇, a single electron completely reverses the potential energy surface of this system. All three structures have the heteroatomic ring B₃O₃ as their key structural. The terminal OBO ligand also has a double 3c–4e high valent π-bond.

As smart materials, electrorheological elastomers (EREs) formed by pre-treating active electrorheological particles are attracting more and more attention. In this work, four Mg-doped strontium titanate (Mg-STO) particles with spherical, dendritic, flake-like, and pinecone-like morphologies were obtained via hydrothermal and low-temperature co-precipitation. XRD, SEM, Raman, and FT-IR were used to characterize these products. The results showed that Mg-STOs are about 1.5–2.0 μm in size, and their phase structures are dominated by cubic crystals. These Mg-STOs were dispersed in a hydrogel composite elastic medium. Then, Mg-STO/glycerol/gelatin electrorheological composite hydrophilic elastomers were obtained with or without an electric field. The electric field response properties of Mg-doped strontium titanate composite elastomers were investigated. We concluded that dendritic Mg-STO composite elastomers are high-performance EREs, and the maximum value of their energy storage was 8.70 MPa. The significant electrorheological performance of these products is helpful for their applications in vibration control, force transducers, smart structures, dampers, and other fields.

As a member of smart materials, electrorheological elastomers (EREs) formed by pre-treating active electrorheological particles are attracting more and more attention. In this work, four Mg-doped strontium titanate particles with spherical, dendritic, flake-like and pinecone-like morphorlogies were obtained by hydrothermal and low-temperature co-precipitation. XRD, SEM, Raman and FT-IR were used to characterize the obtained products. The results showed that the sizes of Mg-doped strontium titanates are about 1.5‒2.0 μm, and the phase structure are dominated by cubic crystal. These Mg-doped strontium titanates were dispersed in a hydrogel composite elastic medium. Then, Mg-doped strontium titanate/glycerol/gelatin electrorheological composite hydrophilic elastomers were obtained with or without electric field. The electric field response properties of Mg-doped strontium titanate composite elastomers were investigated. It concluded that dendritic Mg-doped strontium titanate composite elastomers is high-performance EREs. And the maximum value of energy storage modulus of Mg-doped strontium titanate composite elastomers has achieved 8.70 MPa. This high electrorheological performance of the products is helpful for their applications in vibration control, force transducers, smart structures, dampers, and other fields.