Quenching and one- and two-stage aging conditions are found for a high-strength Al-Li-Cu cast alloy with a low density from the results of studying its structure, mechanical properties, and aging kinetics.
Body-centered cubic (BCC) Mg–Li alloy can be effectively strengthened by with the addition of Al and Zn. However, adding excessive amounts result in reduced mechanical properties and damping capacity of the alloy during subsequent heat treatment and deformation. The effects of solution-hot rolling-aging on the mechanical properties and damping capacity of LAZ1333 alloy and LAZ1366 alloy were studied. The solid solution strengthening greatly increases the hardness of the alloy, but the ductility is extremely poor. The AlLi softening phase precipitated during the subsequent hot rolling and aging process greatly improves the ductility of the alloy, but the excess precipitation of in the AlLi softening phase and the solid solution of excess Zn element are not conducive to the substantial improvement of the strength and ductility of the alloy. Excessive addition of alloying elements is detrimental to the damping capacity of the alloy, but the damping capacity of the alloy can be significantly improved by depleting the number of solute atoms through subsequent ageing treatments. The UTS and FE of as-cast LAZ 1333 alloy are 111 MPa and 16.9%, respectively. The as-aged LAZ1333 alloy has the best mechanical properties and damping capacity, and the UTS and FE are increased by 65.8% and 89.3%, respectively, compared to the as-cast alloy, and the damping capacity increased from 0.011 to 0.015.
The effects of the charge composition, casting method, and metal forming method on the structure and shape-memory-effect (SME) and superelasticity characteristics of titanium nickelide-based alloys are studied. The shape recovery temperatures of semiproducts are shown to depend substantially on the volume fraction of the Ti2Ni intermetallic phase, whose formation is stimulated by the oxygen present in a charge or absorbed during casting. An increase in the volume fraction of Ti2Ni in an alloy leads to nickel enrichment of the B2 phase and a decrease in the shape recovery temperatures. Subsequent metal forming at the stage of semiproduct manufacture only weakly affects the volume fraction of Ti2Ni and favors the formation of its equiaxed shape and a more uniform Ti2Ni distribution in the B2 matrix. In alloys where the B2 phase contains more than 56.5 wt % Ni, quenching from temperatures above 600°C and aging in the temperature range 400–500°C result in the dissolution and precipitation, respectively, of the nickel-rich Ti3Ni4 and Ti2Ni3 intermetallics. Therefore, the shape recovery temperatures of semiproducts and finished products can be controlled. Moreover, as the aging temperature changes, the volume fraction and size of nickel-rich intermetallic particles, the slip stresses, and the SME force characteristics change. For example, to increase the compression forces for osteosynthesis fixation devices, one has to use a titanium nickelide-based alloy with a high nickel content in the B2 phase and to perform aging at low temperatures (400–450°C).
Al-Li alloys are considered. A quantitative approach to the determination of the ratio of the fractions of the binary and ternary intermetallic phases in Al-Mg(Cu)-Li alloys is developed on the basis of chemical and phase composition balance equations and the experimentally measured lattice parameter of the α solid solution. The ratio of the fractions of the δ′(Al3Li) and S1(T1) phases in Al-Mg(Cu)-Li alloys is shown to be determined by the ratio of the mole fractions of Li and Mg(Cu). Equations are proposed for calculating the weight fractions of the S1(Al2MgLi), T1(Al2CuLi) and δ′(Al3Li) phases in domestic and foreign Al-Mg-Li alloys 1420, 1424, 5090 and Al-Cu-Li alloys 1440, 1460, 1461, 1441, 1469, 2090, 2095, 8090, and Weldalite 049.