Paleoclimate studies play a crucial role in understanding past and future climates and their environmental impacts. Current methodologies for performing highly sensitive elemental analysis at micrometre spatial resolutions are restricted to the use of complex and/or not easily applied techniques, such as synchrotron radiation X-ray fluorescence micro-analysis (μ-SRXRF), nano secondary ion mass spectrometry (nano-SIMS) or laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Moreover, the analysis of large samples (>few cm²) with any of these methods remains very challenging due to their relatively low acquisition speed (~1–10 Hz), and because they must be operated in vacuum or controlled atmosphere. In this work, we proposed an imaging methodology based on laser-induced breakdown spectroscopy, to perform fast multi-elemental scanning of large geological samples with high performance in terms of sensitivity (ppm-level), lateral resolution (up to 10 μm) and operating speed (100 Hz). This method was successfully applied to obtain the first megapixel images of large geological samples and yielded new information, not accessible using other techniques. These results open a new perspective into the use of laser spectroscopy in a variety of geochemical applications.

Despite the multiple impacts of mineral aerosols on global and regional climate and the primary climatic control on atmospheric dust fluxes, dust-climate feedbacks remain poorly constrained, particularly at submillennial time scales, hampering regional and global climate models. We reconstruct Saharan dust fluxes over Western Europe for the last 5000 years, by means of speleothem strontium isotope ratios (⁸⁷Sr/⁸⁶Sr) and karst modeling. The record reveals a long-term increase in Saharan dust flux, consistent with progressive North Africa aridification and strengthening of Northern Hemisphere latitudinal climatic gradients. On shorter, centennial to millennial scales, it shows broad variations in dust fluxes, in tune with North Atlantic ocean-atmosphere patterns and with monsoonal variability. Dust fluxes rapidly increase before (and peaks at) Late Holocene multidecadal- to century-scale cold climate events, including those around 4200, 2800, and 1500 years before present, suggesting the operation of previously unknown strong dust-climate negative feedbacks preceding these episodes.