In agriculture, reducing herbicide use is a challenge to reduce health and environmental risks while maintaining production yield and quality. Site-specific weed management is a promising way to reach this objective but requires efficient weed detection methods. In this paper, an automatic image processing has been developed to discriminate between crop and weed pixels combining spatial and spectral information extracted from four-band multispectral images. Image data was captured at 3 m above ground, with a camera (multiSPEC 4C, AIRINOV, Paris) mounted on a pole kept manually. For each image, the field of view was approximately 4 m × 3 m and the resolution was 6 mm/pix. The row crop arrangement was first used to discriminate between some crop and weed pixels depending on their location inside or outside of crop rows. Then, these pixels were used to automatically build the training dataset concerning the multispectral features of crop and weed pixel classes. For each image, a specific training dataset was used by a supervised classifier (Support Vector Machine) to classify pixels that cannot be correctly discriminated using only the initial spatial approach. Finally, inter-row pixels were classified as weed and in-row pixels were classified as crop or weed depending on their spectral characteristics. The method was assessed on 14 images captured on maize and sugar beet fields. The contribution of the spatial, spectral and combined information was studied with respect to the classification quality. Our results show the better ability of the spatial and spectral combination algorithm to detect weeds between and within crop rows. They demonstrate the improvement of the weed detection rate and the improvement of its robustness. On all images, the mean value of the weed detection rate was 89% for spatial and spectral combination method, 79% for spatial method, and 75% for spectral method. Moreover, our work shows that the plant in-line sowing can be used to design an automatic image processing and classification algorithm to detect weed without requiring any manual data selection and labelling. Since the method required crop row identification, the method is suitable for wide-row crops and high spatial resolution images (at least 6 mm/pix).

The study of chemical reactions in clusters is a rapidly growing field that is attractive for investigating medium effects in reaction dynamics. Cluster isolated chemical reaction (CICR) is a new direction developed in our laboratory, which enables quantitative studies to be made in that field. CICR experiments consist in depositing a controlled number of reactants on large van der Waals clusters that play the role of a solvent of fairly well known size, structure and temperature. This offers enormous advantages, both on the experimental side and for further theoretical investigations. The present review intends to draw together informations that are pertinent for developing experiments and concepts towards understanding chemical reactions in clusters, through CICR-type experiments. In particular, it reviews the questions first of generating and controlling the properties of large van der Waals clusters and secondly of attaching reactants to clusters and controlling their number and location in the cluster. Besides reviewing thoroughly the CICR work done so far in our laboratory, the present paper also reviews part of the vast literature pertaining to reaction dynamics in large van der Waals clusters.

In precision agriculture, the development of proximal imaging systems embedded in autonomous vehicles allows to explore new weed management strategies for site-specific plant application. Accurate monitoring of weeds while controlling wheat growth requires indirect measurements of leaf area index (LAI) and above-ground dry matter biomass (BM) at early growth stages. This article explores the potential of RGB images to assess crop-weed competition in a wheat (Triticum aestivum L.) crop by generating two new indicators, the weed pressure (WP) and the local wheat biomass production ($\mathsf{\delta }\mathrm{BMc}$). The fractional vegetation cover (FVC) of the crop and the weeds was automatically determined from the images with a SVM-RBF classifier, using bag of visual word vectors as inputs. It is based on a new vegetation index called MetaIndex, defined as a vote of six indices widely used in the literature. Beyond a simple map of weed infestation, the map of WP describes the crop-weed competition. The map of δBMc, meanwhile, evaluates the local wheat above-ground biomass production and informs us about a potential stress. It is generated from the wheat FVC because it is highly correlated with LAI (r² = 0.99) and BM (r² = 0.93) obtained by destructive methods. By combining these two indicators, we aim at determining whether the origin of the wheat stress is due to weeds or not. This approach opens up new perspectives for the monitoring of weeds and the monitoring of their competition during crop growth with non-destructive and proximal sensing technologies in the early stages of development.