Emergency water release from underground reservoirs is characterized by its suddenness and significant harm. The quantitative prediction of water spreading processes in mine tunnels is crucial for enhancing underground safety. The study focuses on an underground roadway in a coal mine, constructing a three-dimensional physical model of the complex tunnel network to explore the spatiotemporal characteristics of water flow spreading after water release in coal mine tunnels. The Volume of Fluid (VOF) model of the Eulerian multiphase flow was adopted to simulate the flow state of water in the roadway. The results indicate that after water release from the reservoir, water flows along the tunnel network towards locations with relatively lower altitude terrain. During the initial stage of water release, sloping tunnels act as barriers to water spreading. The water level height at each point in the tunnel network generally experiences three developmental stages: rapid rise, slow increase, and stable equilibrium. The water level height in the tunnel area near the water release outlet rises sharply within a time range of 550 s; tunnels farther from the water release outlet experience a rapid rise in water level height only after 13,200 s. The final stable equilibrium water level in the tunnel depends on the location of the water release outlet and the relative height of the terrain, with a water level height ranging from 0.3 to 3.3 m. The maximum safe evacuation time for personnel within a radius of 300 m from the drainage outlet is only 1 h. In contrast, areas farther away from the drainage location benefit from the water storage capacity of the complex tunnel network and have significantly extended evacuation opportunities.

To maximize the comprehensive utilization of gangue waste, broken gangue can be used to replace gravel as the coarse aggregate to prepare underground roadway shotcrete, and treated gangue powder can be used for the partial replacement of cement. This not only diminishes the demand for conventional raw materials but also increases the amount of gangue waste disposed. Broken gangue waste was ball-milled for 1 h, 3 h, and 5 h to prepare gangue powder, which was used to partially replace cement. Then, experimental schemes for the performance of shotcrete at the rates of cement replacement of 30%, 40%, and 50% were devised to compare the mineral compositions and microscopic characteristics of shotcrete with the partial replacement of cement with gangue powder. The influences of the partial replacement of cement with gangue powder on the slump, tensile strength, and compressive strength of the shotcrete were revealed. The experimental results revealed an inverse relationship between shotcrete slump and both the cement replacement ratio and the gangue Ball-milling duration. Increasing the cement replacement ratio from 30% to 50% reduced slump by 55.3% (103 mm → 46 mm), while extending the Ball-milling time from 1 h to 5 h decreased it by 33.0% (103 mm → 69 mm). Mechanical properties showed contrasting trends: After a 28-day curing process, compressive and tensile strengths declined by 54.5% (20.18 → 9.18 MPa) and 40.4% (1.56 → 0.93 MPa), respectively, with a higher cement replacement ratio. Conversely, prolonged Ball-milling duration improved the compressive strength by 12.8% (18.68 → 21.07 MPa) and the tensile strength by 34.1% (1.26 → 1.69 MPa). Moreover, the shotcrete meets the strength requirements for engineering applications only when the cement replacement ratio is 30% with gangue ball-milling durations of 3 h and 5 h. The research provides strong support for the performance optimization of gangue-based shotcrete and the improvement of the utilization of gangue waste.

Hydrothermal treatment has been demonstrated as a highly effective approach to enhance the adsorption properties of coal gangue (CG) for Cd²⁺ and Pb²⁺. This study evaluated the influence of NaOH concentration (X₁), hexadecyltrimethylammonium bromide dosage (X₂) and hydrothermal duration (X₃) on the modified CG’s composition and its adsorption capacities for Cd²⁺ (q_e,Cd) and Pb²⁺ (q_e,Pb). Response Surface Methodology (RSM) was utilized to explore the interactions among these variables, while XRD, SEM-EDX, FTIR and XPS techniques were employed to elucidate the adsorption mechanisms. The results reveal that hydrothermal treatment facilitated the formation of zeolite materials in the modified CG samples. Optimal conditions for Cd²⁺ adsorption (q_e,Cd = 58.4 mg/g) were determined as X₁ = 2.9 mol/L, X₂ = 1 g and X₃ = 16.8 h. For Pb²⁺ adsorption (q_e,Pb = 233.6 mg/g), the optimal conditions were X₁ = 2.4 mol/L, X₂ = 0.57 g and X₃ = 20.7 h. RSM analysis indicated that X₃ significantly influences q_e,Cd with the appropriate range of 14–18 h, while all three factors (X₁, X₂ and X₃) notably affect q_e,Pb, with suitable ranges identified as follows: X₁ = 1.8–3 mol/L, X₂ = 0.4–0.8 g and X₃ = 16–24 h. The primary adsorption mechanism for Cd²⁺ and Pb²⁺ was determined to be ion exchange, with additional Pb²⁺ removal achieved through the precipitation of cerussite (PbCO₃).