Microbial infections lead to elevated inflammatory responses, which usually result in prolonged and incomplete wound healing. Therefore, there is an increasing demand for biodegradable fibres that are effective against a different range of microorganisms, especially those with antibiotic resistance. Herein, quercetin-(Q)-loaded polylactide-based fibres were developed using the electrospinning technique. Since Q exhibits low chemical stability, we used star-shaped polylactides (PLAs) with a β-CD core to host Q by inclusion complexation. To enhance the stability of the fibres and additionally entrap the Q between polymeric chains, we adapted supramolecular cross-linking by the stereocomplexation of PLAs with opposite configurations. As a control, we prepared an additional formulation of star-shaped/commercial PLA/Q for the preparation of nonwovens in which the β-CD moiety was not present. All developed fibres were smooth and continuous, with an average diameter of 37 μm. Although nonwovens did not possess diffusible activity, good antibacterial effects against Staphylococcus aureus (S. aureus), Escherichia coli (E.coli) and Klebsiella pneumoniae (K. pneumoniae) were observed. All these features validate the proposed approach, in which different supramolecular interactions were used to modify the properties of PLA-based fibres and, most importantly, show their great potential usefulness against microbial infections.
Cotton fabrics were modified by xerogel coatings with dispersed particles of graphene (Gr) or reduced graphene oxide (RGO). To obtain a stable dispersion of Gr or RGO in organo-silicon sol, sodium lauryl sulfate as an anionic surfactant was used. The fabrics were padded with the organo-silicon sol containing dispersed Gr or RGO, forming a thin xerogel coating after drying. The fabrics coated with the xerogel containing 0.5–1.5 wt% of RGO or Gr were prepared and examined. The best anti-static properties were obtained for the coating with 1.5 wt% of Gr, whose surface resistance and volume resistance were on the order of 105 and 103 Ω, respectively. Such properties make the fabric suitable for protective cloths in the environment with explosive atmosphere.
This article presents the findings concerning the preparation and properties of cotton woven fabrics with a conductive network made of multiwall carbon nanotubes deposited on the fiber surface by the padding method. The next stage of treatment consisted of imparting superhydrophobic properties to the fabrics in solution with methyltrichlorosilane (MTCS) in a waterless medium. The tests performed show that the state of surface and water content in cotton fibers exerts a significant influence on the hydrophobic properties of the analyzed samples. In order to explain the differences in hydrophobic properties, the morphology of the cotton fabric surface was examined using samples with various water contents. The formation mechanism of MTCS coatings on cotton fabric has been proposed.