Quantitative chemical analysis of airborne particulate matter (PM) is vital for the understanding of health effects in indoor and outdoor environments, as well as for enforcing EU air quality regulations. Typically, airborne particles are sampled over long time periods on filters, followed by lab-based analysis, e.g., with inductively coupled plasma mass spectrometry (ICP-MS). During the EURAMET EMPIR AEROMET project, cascade impactor aerosol sampling is combined for the first time with on-site total reflection X-ray fluorescence (TXRF) spectroscopy to develop a tool for quantifying particle element compositions within short time intervals and even on-site. This makes variations of aerosol chemistry observable with time resolution only a few hours and with good size resolution in the PM₁₀ range. The study investigates the proof of principles of this methodological approach. Acrylic discs and silicon wafers are shown to be suitable impactor carriers with sufficiently smooth and clean surfaces, and a non-destructive elemental mass concentration measurement with a lower limit of detection around 10 pg/m³ could be achieved. We demonstrate the traceability of field TXRF measurements to a radiometrically calibrated TXRF reference, and the results from both analytical methods correspond satisfactorily.

Urban transportation is a key contributor to air pollution in cities. While urban buses impact air quality, they also promote sustainable mobility. In the Paris region, buses account for approximately 4% of traffic emissions. This study addresses the gap in real-world emissions data for Euro VI diesel, diesel-hybrid, and compressed natural gas (CNG) urban buses by developing speed-dependent emission factors for CO, NO_X, SPN₂₃, and energy consumption. An optimized methodology was applied to portable emission measurement system data collected from 28 urban buses across various routes in the Paris metropolitan area, capturing emissions across different speeds and traffic conditions. Results showed that diesel buses emit around 2 g/km of NOx at low speeds, compared to 1.4 g/km for diesel hybrids and 0.6 g/km for CNG. CO emissions reached approximately 1 g/km for CNG and 0.5 g/km for diesel, while SPN₂₃ emissions for all powertrains were in the order of 10¹² particles/km. The resulting speed-dependent emission factors were incorporated into COPERT version 5.8, the European Union’s standard emission inventory software, improving the inventory accuracy. The findings underscore the need for additional reductions in air pollutant emissions to meet Euro 7 standards and provide a robust framework for improving air quality management.